Title : ( N,N,N-,N- -Tetrabenzyl-N-- -(2,6-difluoro- benzoyl)phosphoric triamide )
Authors: Akbar Raissi Shabari , Mehrdad Pourayoubi , Atekeh Tarahhomi , Arnold L. Rheingold , James A. Golen ,
Full TextAbstract
In the C(O)NHP(O) fragment of the title compound, C35H32F2N3O2P, the P—N bond is longer and the O—P—N angle is contracted compared with the other two P—N bonds and O—P—N angles. The P atom adopts a distorted tetrahedral environment and the phosphoryl and carbonyl groups are anti with respect to each other. The two tertiary N atoms of the dibenzylamido groups show sp2 character with a slight deviation from planarity. In the crystal, pairs of N—H…O(P) hydrogen bonds form inversion dimers.
Keywords
, single, crystal X, ray study; T = 100 K; mean σ(C–C) = 0.003 Å; R factor = 0.044; wR factor = 0.111; data, to, parameter ratio = 15.9.
@article{paperid:1030506,
author = {Akbar Raissi Shabari and Pourayoubi, Mehrdad and Tarahhomi, Atekeh and Arnold L. Rheingold and James A. Golen},
title = {N,N,N-,N- -Tetrabenzyl-N-- -(2,6-difluoro- benzoyl)phosphoric triamide},
journal = {Acta Crystallographica Section E: Structure Reports Online},
year = {2012},
volume = {68},
number = {11},
month = {November},
issn = {1600-5368},
pages = {3186--3186},
numpages = {0},
keywords = {single-crystal X-ray study; T = 100 K; mean σ(C–C) = 0.003 Å; R factor = 0.044; wR factor = 0.111; data-to-parameter ratio = 15.9.},
}
%0 Journal Article
%T N,N,N-,N- -Tetrabenzyl-N-- -(2,6-difluoro- benzoyl)phosphoric triamide
%A Akbar Raissi Shabari
%A Pourayoubi, Mehrdad
%A Tarahhomi, Atekeh
%A Arnold L. Rheingold
%A James A. Golen
%J Acta Crystallographica Section E: Structure Reports Online
%@ 1600-5368
%D 2012
