Title : ( Hexakis{[1-(dimethylamino)propylidene]oxidanium} bis(dodecamolybdophosphate)N,N-dimethylpropionamide pentasolvate )
Authors: Akbar Raissi Shabari , Mehrdad Pourayoubi , Shadi Derakhshan Rad ,
Full TextAbstract
In the asymmetric unit of the title salt, (C5H12NO)6[PMo12O40]2.5C5H11NO, there are two independent α-Keggin-type [PMo12O40]3– polyoxidoanions, which show characteristic features with respect to bond lengths and angles. One of the [CH3CH2C(═OH)N(CH3)2]+ cations is hydrogen bonded to the neighboring polyoxidoanion through a C═O—H…Obridge hydrogen bond. The organic molecules and the remaining organic cations form [(C5H11NO)2H]+ molecule–cation pairs, two of which lie about inversion centers, through O—H…O hydrogen bonds.
Keywords
, single, crystal X, ray study; T = 100 K; mean σ(C–C) = 0.016 Å; R factor = 0.055; wR factor = 0.091; data, to, parameter ratio = 17.6.
@article{paperid:1030650,
author = {Akbar Raissi Shabari and Pourayoubi, Mehrdad and Shadi Derakhshan Rad},
title = {Hexakis{[1-(dimethylamino)propylidene]oxidanium} bis(dodecamolybdophosphate)N,N-dimethylpropionamide pentasolvate},
journal = {Acta Crystallographica Section E: Structure Reports Online},
year = {2012},
volume = {68},
number = {9},
month = {September},
issn = {1600-5368},
keywords = {single-crystal X-ray study; T = 100 K; mean σ(C–C) = 0.016 Å; R factor = 0.055; wR factor = 0.091; data-to-parameter ratio = 17.6.},
}
%0 Journal Article
%T Hexakis{[1-(dimethylamino)propylidene]oxidanium} bis(dodecamolybdophosphate)N,N-dimethylpropionamide pentasolvate
%A Akbar Raissi Shabari
%A Pourayoubi, Mehrdad
%A Shadi Derakhshan Rad
%J Acta Crystallographica Section E: Structure Reports Online
%@ 1600-5368
%D 2012
