Journal of Natural Gas Science and Engineering, ( ISI ), Volume (14), Year (2013-6) , Pages (29-33)

Title : ( Study of activity, products selectivity and physico-chemical properties of bifunctional Fe/HZSM-5 FischereTropsch catalyst: Effect of catalyst shaping )

Authors: Ali Nakhaei Pour , Mohammad Reza Housaindokht ,

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Abstract

Fe/Cu/La/Si catalyst was prepared by co-precipitation, mixed with HZSM-5 zeolite and shaped to cylinders form by a binder for increasing the mechanical strength of bifunctional catalyst. Activity of the prepared Fe/HZSM5 in syngas conversion to hydrocarbons was studied in a fixed bed micro reactor. The influence of binders on the catalyst performance, physico-chemical properties and products selectivity of bifunctional Fe/HZSM-5 catalyst was studied under reaction condition, P ¼ 1.7 MPa, T ¼ 563 K, H2/CO ¼ 1 and GHSV ¼ 5.04 nl h1 g1 Fe. The results showed that the catalyst activity for FischereTropsch synthesis and water-gas-shift reactions was enhanced by the alumina binders in comparison to the silica binders and also secondary reactions in the presence of alumina were occurred rather than silica.

Keywords

, FischereTropsch synthesis, HZSM-5 zeolite, Iron catalysts, Binder