Title : ( Green and Selective Synthesis ofN-Substituted Amides using Water Soluble Porphyrazinato Copper(II) Catalyst )
Authors: sara sadat emam jomae ghodsinia , Batool Akhlaghinia , Elham Safaei , Hossein Eshghi ,
Full TextAbstract
N,N’,N’’,N’’’-Tetramethyl tetra-2,3-pyridinoporphyrazinato copper(II) methyl sulfate ([Cu(2,3‑tmtppa)](MeSO4)4) efficiently catalyzed the direct conversion of nitriles to N-substituted amides. The one pot selective synthesis of the N-substituted amides from nitriles and primary amines was performed in refluxing H2O. The catalyst was recovered and reused at least four times, maintaining its efficiency.
Keywords
, [Cu(2, 3-tmtppa)](MeSO4)4, N-substituted amide, nitrile, amine
@article{paperid:1035014,
author = {Emam Jomae Ghodsinia, Sara Sadat and Akhlaghinia, Batool and Elham Safaei and Eshghi, Hossein},
title = {Green and Selective Synthesis ofN-Substituted Amides using Water Soluble Porphyrazinato Copper(II) Catalyst},
journal = {Journal of the Brazilian Chemical Society},
year = {2013},
volume = {24},
number = {6},
month = {January},
issn = {0103-5053},
pages = {895--903},
numpages = {8},
keywords = {[Cu(2;3-tmtppa)](MeSO4)4; N-substituted amide; nitrile; amine},
}
%0 Journal Article
%T Green and Selective Synthesis ofN-Substituted Amides using Water Soluble Porphyrazinato Copper(II) Catalyst
%A Emam Jomae Ghodsinia, Sara Sadat
%A Akhlaghinia, Batool
%A Elham Safaei
%A Eshghi, Hossein
%J Journal of the Brazilian Chemical Society
%@ 0103-5053
%D 2013
