20th Iranian Seminar of Organic Chemistry , 2013-07-03

Title : ( A Facile Approach for the Synthesis of Novel Macrocycles of Spiroorthocarbonates )

Authors: Ali Shiri , Mohammad Rahimizadeh , Mehdi Bakavoli , Hossein Eshghi ,

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Spiroorthocarbonates (SOCs) are one of the most important categories of monomers which polymerize without any shrinkage in volume.[1] They are specially useful in the synthesis of materials such as precision materials, adhesives, and dental composites.[1-3] On the other hand, molecular iodine has been the focus of attention in organic transformations as a mild, readily available and neutral Lewis acid.[4] In this study, some novel spiro macrocycles derived from spiroorthocarbonates were conducted to synthesize. In this protocol, 2,2-diphenoxy-1,3-dioxanes were prepared from the reaction of dichlorodiphenoxymathane with some 1,3-dioles at room temperature. Then, the treatment of compounds 1(a,b) with various glycols 2(a-c) in the presence of catalytic molar ratio of molecular iodine obtain the corresponding novel macrocylces of spiroorthocarbonates 3(a-f) in good yields.

Keywords

, Facile Approach, Macrocycles,
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@inproceedings{paperid:1035292,
author = {Shiri, Ali and Rahimizadeh, Mohammad and Bakavoli, Mehdi and Eshghi, Hossein},
title = {A Facile Approach for the Synthesis of Novel Macrocycles of Spiroorthocarbonates},
booktitle = {20th Iranian Seminar of Organic Chemistry},
year = {2013},
location = {همدان, IRAN},
keywords = {Facile Approach; Macrocycles; Spiroorthocarbonates},
}

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%0 Conference Proceedings
%T A Facile Approach for the Synthesis of Novel Macrocycles of Spiroorthocarbonates
%A Shiri, Ali
%A Rahimizadeh, Mohammad
%A Bakavoli, Mehdi
%A Eshghi, Hossein
%J 20th Iranian Seminar of Organic Chemistry
%D 2013

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