Title : ( Synthesis, structural, and thermal analyses of copper(II) and oxido-vanadium(IV) complexes of 4-bromo-2-(((5-chloro-2- hydroxyphenyl)imino)methyl)phenol )
Authors: Reza Takjoo , J. T. Mague , A. Akbari , S. Y. Ebrahimipour ,
Full TextAbstract
Reaction of 4-bromo-2-(((5-chloro-2-hydroxyphenyl)imino)methyl)phenol (H2L) with Cu(OAc)2·4H2O or VOSO4·3H2O and 2,2′-bipyridine (bipy) or 1,10-phenanthroline (phen) in a 1 : 1 : 1mol ratio led to [CuL(phen)] and [VOL(bipy)] which have distorted square pyramidal and octahedral geometries, respectively. The compounds were characterized by elemental analyses, FT-IR, UV–Vis, TGA, and X-ray diffraction. Their thermolyses have three stages: phen or bipy removal, separation of H2L minus chloride and bromide of H2L, and complete thermal decomposition to the metal oxide.
Keywords
, Oxido, vanadium(IV) complex; Copper(II) complex; TGA; Spectroscopy; Crystal structures
@article{paperid:1035306,
author = {Takjoo, Reza and J. T. Mague and A. Akbari and S. Y. Ebrahimipour},
title = {Synthesis, structural, and thermal analyses of copper(II) and oxido-vanadium(IV) complexes of 4-bromo-2-(((5-chloro-2- hydroxyphenyl)imino)methyl)phenol},
journal = {Journal of Coordination Chemistry},
year = {2013},
volume = {66},
number = {16},
month = {July},
issn = {0095-8972},
pages = {2852--2862},
numpages = {10},
keywords = {Oxido-vanadium(IV) complex; Copper(II) complex; TGA; Spectroscopy; Crystal structures},
}
%0 Journal Article
%T Synthesis, structural, and thermal analyses of copper(II) and oxido-vanadium(IV) complexes of 4-bromo-2-(((5-chloro-2- hydroxyphenyl)imino)methyl)phenol
%A Takjoo, Reza
%A J. T. Mague
%A A. Akbari
%A S. Y. Ebrahimipour
%J Journal of Coordination Chemistry
%@ 0095-8972
%D 2013
