Journal of Natural Gas Science and Engineering, ( ISI ), Volume (15), No (5), Year (2013-11) , Pages (53-58)

Title : ( Mechanistic double ASF product distribution study of Fischer-Tropsch Synthesis on precipitated iron catalyst )

Authors: Ali Nakhaei Pour , hamideh khodabandeh baygi , Mohammad Izadyar , Mohammad Reza Housaindokht ,

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Product distributions of iron based catalyst represented by double ASF distributions characterized by two growth probabilities. Based on enol mechanism and double ASF distributions the complete set of elementary reactions is given. By using mechanistic kinetic studies of Fischer-Tropsch reaction, the chain growth probabilities (α1 and α2) for double ASF distributions is formulated. Fe-Cu–La catalyst was prepared by co-precipitation procedure, and steady-state FTS reaction rates were measured in a continuous spinning basket reactor. The experimental results for low carbon monoxide conversions have been satisfactorily fit with the double ASF model. But for higher carbon monoxide conversions deviate substantially because the FTS reaction highly depends on the hydrogen formed by the WGS as the carbon monoxide conversion increases.

Keywords

Iron catalysts; Kinetics; Products data; Double ASF
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@article{paperid:1036583,
author = {Nakhaei Pour, Ali and Khodabandeh Baygi, Hamideh and Izadyar, Mohammad and Housaindokht, Mohammad Reza},
title = {Mechanistic double ASF product distribution study of Fischer-Tropsch Synthesis on precipitated iron catalyst},
journal = {Journal of Natural Gas Science and Engineering},
year = {2013},
volume = {15},
number = {5},
month = {November},
issn = {1875-5100},
pages = {53--58},
numpages = {5},
keywords = {Iron catalysts; Kinetics; Products data; Double ASF distributions},
}

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%0 Journal Article
%T Mechanistic double ASF product distribution study of Fischer-Tropsch Synthesis on precipitated iron catalyst
%A Nakhaei Pour, Ali
%A Khodabandeh Baygi, Hamideh
%A Izadyar, Mohammad
%A Housaindokht, Mohammad Reza
%J Journal of Natural Gas Science and Engineering
%@ 1875-5100
%D 2013

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