Title : ( Ionic liquids bis(2-N-methylimidazoliumethyl)ether dichloroiodate/dibromochlorate as an efficient halogenating reagent for the synthesis of a-haloketones )
Authors: Hossein Eshghi , Mehdi Bakavoli , marjan ghasemzadeh , Seyed Mohammad Seyedi ,
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Abstract
Bis(2-N-methylimidazoliumethyl)ether dichloroiodate/dibromochlorate is found to be an effective reagent system for the a-chlorination/bromination of carbonyl compounds. These novel solid halogenating reagents are readily prepared from an ionic liquid and molecular halogen in high yields. a-halogenation reaction occurs under mild conditions yielding the products in good to excellent yields.
Keywords
, a-Halogenation , Ionic liquids, Ketones, Dichloroiodate, Dibromochlorate
@article{paperid:1037913,
author = {Eshghi, Hossein and Bakavoli, Mehdi and Ghasemzadeh, Marjan and Seyedi, Seyed Mohammad},
title = {Ionic liquids bis(2-N-methylimidazoliumethyl)ether dichloroiodate/dibromochlorate as an efficient halogenating reagent for the synthesis of a-haloketones},
journal = {Research on Chemical Intermediates},
year = {2015},
volume = {41},
number = {3},
month = {March},
issn = {0922-6168},
pages = {1673--1682},
numpages = {9},
keywords = {a-Halogenation ; Ionic liquids; Ketones; Dichloroiodate; Dibromochlorate},
}
%0 Journal Article
%T Ionic liquids bis(2-N-methylimidazoliumethyl)ether dichloroiodate/dibromochlorate as an efficient halogenating reagent for the synthesis of a-haloketones
%A Eshghi, Hossein
%A Bakavoli, Mehdi
%A Ghasemzadeh, Marjan
%A Seyedi, Seyed Mohammad
%J Research on Chemical Intermediates
%@ 0922-6168
%D 2015
