Title : ( [(Pyridine-2,6-dicarboxylato)copper(II)]- l-(pyridine-2,6-dicarboxylato)-[bis(ethylenediamine) copper(II)]-l-(pyridine-2,6- dicarboxylato)-[(pyridine-2,6-dicarboxylato) copper(II)] ethylenediamine monosolvate tetrahydrate )
Authors: Amir SHokooh Saljooghi , Hadi Amiri Rudbari , Francesco Nicolo , malihe zahmati eiraj , fatemeh delavar mendi ,
Full TextAbstract
The title compound, [Cu3(C7H3NO4)4(C2H8N2)2]C2H8N2- 4H2O, was obtained by the reaction of copper(II) acetate dihydrate with pyridine-2,6-dicarboxylic acid (H2dipic) and ethylenediamine (en) in an aqueous solution. All of the CuII atoms in the trinuclear centrosymmetric title complex are sixcoordinated in a distorted octahedral geometry with N2O4 and N4O2 environments for the outer and central CuII atoms, respectively. Various interactions, including numerous O— H O and C—H O hydrogen bonds and C—O stacking of the pyridine and carboxylate groups [O centroid distances = 3.669 (2) and 3.668 (2) A ° ] are observed in the crystal structure.
Keywords
, Key indicators: single, crystal X, ray study; T = 293 K; mean (C–C) = 0.002 A° ; R factor = 0.035; wR factor = 0.100; data, to, parameter ratio = 28.1.
@article{paperid:1038686,
author = {SHokooh Saljooghi, Amir and Hadi Amiri Rudbari and Francesco Nicolo and Zahmati Eiraj, Malihe and Delavar Mendi, Fatemeh},
title = {[(Pyridine-2,6-dicarboxylato)copper(II)]- l-(pyridine-2,6-dicarboxylato)-[bis(ethylenediamine) copper(II)]-l-(pyridine-2,6- dicarboxylato)-[(pyridine-2,6-dicarboxylato) copper(II)] ethylenediamine monosolvate tetrahydrate},
journal = {Acta Crystallographica Section E: Structure Reports Online},
year = {2012},
volume = {68},
number = {1},
month = {April},
issn = {1600-5368},
pages = {830--831},
numpages = {1},
keywords = {Key indicators: single-crystal X-ray study; T = 293 K; mean (C–C) = 0.002 A°
;
R factor = 0.035; wR factor = 0.100; data-to-parameter ratio = 28.1.},
}
%0 Journal Article
%T [(Pyridine-2,6-dicarboxylato)copper(II)]- l-(pyridine-2,6-dicarboxylato)-[bis(ethylenediamine) copper(II)]-l-(pyridine-2,6- dicarboxylato)-[(pyridine-2,6-dicarboxylato) copper(II)] ethylenediamine monosolvate tetrahydrate
%A SHokooh Saljooghi, Amir
%A Hadi Amiri Rudbari
%A Francesco Nicolo
%A Zahmati Eiraj, Malihe
%A Delavar Mendi, Fatemeh
%J Acta Crystallographica Section E: Structure Reports Online
%@ 1600-5368
%D 2012
