Title : ( Conductometric Study of Complex Formation between Benzylbisthiosemicarbazone and Metal Cations in Acetonitrile, Dimethylformamide, and Their Binary Mixtures )
Authors: Hamideh Sharifi Noghabi , Gholam hossein Ronaghi , Mohammad Hossein Arbab Zavar , جواد ابراهیمی ,
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Abstract
We report on conductometric study of complexation between benzylbisthiosemicarbazone [(2E,2'E)-2,2'-(1,2-diphenylethane-1,2-diylidene)bis(hydrazine-1-carbothioamide)] with Zn2+, Cr3+, Co2+, and Ni2+cations at different temperatures in acetonitrile–dimethylformamide binary solvents of varied composition. The equilibrium constant and standard thermodynamic parameters (ΔcH0 and ΔcS0) of the complexes formation have been determined and found to be dependent on the binary solvent composition, the metal ion nature, and temperature.
Keywords
, metal cation, benzylbisthiosemcarbazone, acetonitrile, dimethylformamide, binary solvent, conductometry
@article{paperid:1045983,
author = {Sharifi Noghabi, Hamideh and Ronaghi, Gholam Hossein and Arbab Zavar, Mohammad Hossein and جواد ابراهیمی},
title = {Conductometric Study of Complex Formation between Benzylbisthiosemicarbazone and Metal Cations in Acetonitrile, Dimethylformamide, and Their Binary Mixtures},
journal = {Russian Journal of General Chemistry},
year = {2014},
volume = {84},
number = {7},
month = {March},
issn = {1070-3632},
pages = {1429--1433},
numpages = {4},
keywords = {metal cation; benzylbisthiosemcarbazone; acetonitrile; dimethylformamide; binary solvent; conductometry},
}
%0 Journal Article
%T Conductometric Study of Complex Formation between Benzylbisthiosemicarbazone and Metal Cations in Acetonitrile, Dimethylformamide, and Their Binary Mixtures
%A Sharifi Noghabi, Hamideh
%A Ronaghi, Gholam Hossein
%A Arbab Zavar, Mohammad Hossein
%A جواد ابراهیمی
%J Russian Journal of General Chemistry
%@ 1070-3632
%D 2014
