Title : ( Synthesis, molecular structure, spectroscopic investigations and computational studies of (E)-1-(4-(4-(diethylamino)-2- hydroxybenzylideneamino)phenyl)ethanone )
Authors: Ayoub Kanaani , Davood Ajloo , Hasan Ghasemian , Hamzeh Kiyani , Mohamad Vakili , Asiyeh Mosallanezhad ,
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Abstract
The Schiff base compound (E)-1-(4-(4-(diethylamino)-2-hydroxybenzylideneamino)phenyl)ethanone has been synthesized and characterized by IR, UV–Vis, and 1H and 13C NMR techniques. These properties of title compound were also investigated from calculative point of view. UV–Vis spectra of the title compound were recorded in different organic solvents to investigate the dependence of tautomerism on solvent types. Calculated results reveal that its enol form is more stable than its keto form. A detailed analysis of the nature of the hydrogen bonding, using topological parameters, evaluated at bond critical points.
Keywords
, Schiff base , Spectroscopy, Intramolecular, proton transfer, DFT
@article{paperid:1047004,
author = {Ayoub Kanaani and Davood Ajloo and Hasan Ghasemian and Hamzeh Kiyani and Vakili, Mohamad and Asiyeh Mosallanezhad},
title = {Synthesis, molecular structure, spectroscopic investigations and computational studies of (E)-1-(4-(4-(diethylamino)-2- hydroxybenzylideneamino)phenyl)ethanone},
journal = {Structural Chemistry},
year = {2015},
volume = {1},
number = {1},
month = {February},
issn = {1040-0400},
pages = {1--19},
numpages = {18},
keywords = {Schiff base ; Spectroscopy; Intramolecular; proton transfer; DFT},
}
%0 Journal Article
%T Synthesis, molecular structure, spectroscopic investigations and computational studies of (E)-1-(4-(4-(diethylamino)-2- hydroxybenzylideneamino)phenyl)ethanone
%A Ayoub Kanaani
%A Davood Ajloo
%A Hasan Ghasemian
%A Hamzeh Kiyani
%A Vakili, Mohamad
%A Asiyeh Mosallanezhad
%J Structural Chemistry
%@ 1040-0400
%D 2015
