Title : ( Non-covalent interactions in tungsten-doped sodium ammonium decavanadate decahydrate )
Authors: Atefeh Najafi , Joel T. Mague , Masoud Mirzaei Shahrabi ,
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Abstract
Partially substituted decavanadate in the title compound [NH4][Na2(H2O)10][V9.7W0.3O28] (1) has been obtained by adding ammonium chloride to the acidic reaction mixture. Single-crystal X-ray analysis shows that the ammonium ions pack in a zigzag fashion constructing a ribbon- like structure in the complex along the ac bisector which can be easily intercalated by sodium dimers to form layers. Finally, the last dimension in the hybrid crystalline network is formed by interactions which make the R4 4 (22) graph set.
Keywords
Decavanadate · Polyoxometalate · Mixed valence · Hydrothermal · Crystal structure
@article{paperid:1053115,
author = {Najafi, Atefeh and Joel T. Mague and Mirzaei Shahrabi, Masoud},
title = {Non-covalent interactions in tungsten-doped sodium ammonium decavanadate decahydrate},
journal = {Journal of the Iranian Chemical Society},
year = {2016},
volume = {13},
number = {4},
month = {February},
issn = {1735-207X},
pages = {773--777},
numpages = {4},
keywords = {Decavanadate · Polyoxometalate · Mixed
valence · Hydrothermal · Crystal structure},
}
%0 Journal Article
%T Non-covalent interactions in tungsten-doped sodium ammonium decavanadate decahydrate
%A Najafi, Atefeh
%A Joel T. Mague
%A Mirzaei Shahrabi, Masoud
%J Journal of the Iranian Chemical Society
%@ 1735-207X
%D 2016
