Title : ( A monomeric copper-phosphoramide complex: Synthesis, structure, and electronic properties )
Authors: Margarida S. Henriques , Denis I. Gorbunov , Alexey N. Ponomaryov , Anahid Saneei , Mehrdad Pourayoubi , Michal Dusek , Sergey Zvyagin , Marc Uhlarz , Joachim Wosnitza ,
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Abstract
We report on a novel phosphoramide complex with formula Cu(NO3)2([C5H10N]3PO)2. This complex is the first example of a copper monomeric phosphoric triamide having an octahedral Cu[O]6 coordination environment. Cu(NO3)2([C5H10N]3PO)2 crystallizes in the monoclinic space group P21/n with the Cu atom located at an inversion center, as determined by single-crystal X-ray diffraction. Magnetic measurements along the principal crystallographic directions of the single crystal indicate that the complex is a paramagnet with very low magnetic anisotropy. Electron paramagnetic resonance spectra reveal the presence of two Cu2+ sites and make it possible to extract the hyperfine coupling.
Keywords
, Phosphoramide, Magnetization, EPR, Mononuclear copper complex
@article{paperid:1058011,
author = {Margarida S. Henriques and Denis I. Gorbunov and Alexey N. Ponomaryov and Saneei, Anahid and Pourayoubi, Mehrdad and Michal Dusek and Sergey Zvyagin and Marc Uhlarz and Joachim Wosnitza},
title = {A monomeric copper-phosphoramide complex: Synthesis, structure, and electronic properties},
journal = {Polyhedron},
year = {2016},
volume = {118},
number = {11},
month = {November},
issn = {0277-5387},
pages = {154--158},
numpages = {4},
keywords = {Phosphoramide; Magnetization; EPR; Mononuclear copper complex},
}
%0 Journal Article
%T A monomeric copper-phosphoramide complex: Synthesis, structure, and electronic properties
%A Margarida S. Henriques
%A Denis I. Gorbunov
%A Alexey N. Ponomaryov
%A Saneei, Anahid
%A Pourayoubi, Mehrdad
%A Michal Dusek
%A Sergey Zvyagin
%A Marc Uhlarz
%A Joachim Wosnitza
%J Polyhedron
%@ 0277-5387
%D 2016
