Title : ( Synthesis, Spectroscopic Investigations, and Computational Study of 4-((9,10-dioxo-9,10-dihydroanthracen-1-yl)oxy)-3- methoxybenzaldehyde1 )
Authors: Ayoub Kanaani , Davood Ajlooa , Hamzeh Kiyani , Mohamad Vakili , Mahnaz Farahani , Majid Amiri ,
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Abstract
4-((9,10-dioxo-9,10-dihydroanthracen-1-yl)oxy)-3-methoxybenzaldehyde has been synthesized in an attempt to obtain a new photochromic compound. The optimized molecular structure, mole fractions of title compound in trans and ana forms have been investigated. UV-visible spectra of the compound were also recorded. Upon irradiation with 300 nm light, the camel solid turned orange, in which a visible absorption band was observed at 475 nm. The electronic properties, such as HOMO, LUMO and band gap energies were obtained by the time-dependent DFT (TD-DFT) approach. The predicted nonlinear optical properties of the title compound are much greater than those of urea. Transition structures were calculated by QST3 and IRC methods which yielded the potential energy surface and activation energy.
Keywords
, Computational Study, 4-((9, 10-dioxo-9, 10-dihydroanthracen-1-yl)oxy)-3- methoxybenzaldehyde
@article{paperid:1058057,
author = {Ayoub Kanaani and Davood Ajlooa and Hamzeh Kiyani and Vakili, Mohamad and Mahnaz Farahani and Majid Amiri},
title = {Synthesis, Spectroscopic Investigations, and Computational Study of 4-((9,10-dioxo-9,10-dihydroanthracen-1-yl)oxy)-3- methoxybenzaldehyde1},
journal = {Optics and Spectroscopy},
year = {2016},
volume = {121},
number = {2},
month = {September},
issn = {0030-400X},
pages = {246--252},
numpages = {6},
keywords = {Computational Study; 4-((9;10-dioxo-9;10-dihydroanthracen-1-yl)oxy)-3-
methoxybenzaldehyde},
}
%0 Journal Article
%T Synthesis, Spectroscopic Investigations, and Computational Study of 4-((9,10-dioxo-9,10-dihydroanthracen-1-yl)oxy)-3- methoxybenzaldehyde1
%A Ayoub Kanaani
%A Davood Ajlooa
%A Hamzeh Kiyani
%A Vakili, Mohamad
%A Mahnaz Farahani
%A Majid Amiri
%J Optics and Spectroscopy
%@ 0030-400X
%D 2016
