Journal of Physical Chemistry B, Volume (112), No (15), Year (2008-4) , Pages (4470-4473)

Title : ( Interdependence of Primary and Johari−Goldstein Secondary Relaxations in Glass-Forming Systems )

Authors: K. Kessair , Capaccio , D. Prevost , M. Lucche , Soheil SHarifi , A. Roll ,

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Abstract

We report evidence from broadband dielectric spectroscopy that the dynamics of the primary α- and secondary Johari−Goldstein (JG) β-processes are strongly correlated in different glass-forming systems over a wide temperature T and pressure P range, in contrast with the widespread opinion of statistical independence of these processes. The α−β mutual dependence is quantitatively confirmed by (a) the overall superposition of spectra measured at different T−P combinations but with an invariant α-relaxation time; (b) the contemporary scaling of the isothermal-pressure and isobaric-temperature dependences of the α-and β-relaxation times as plotted versus the reduced variable Tg(P)/T where Tg is the glass transition temperature. These novel and model-independent evidences indicate the relevance of the JG relaxation phenomenon in glass transition, often overlooked by most current theories.

Keywords

glass transition
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@article{paperid:1058809,
author = {K. Kessair and Capaccio and D. Prevost and M. Lucche and SHarifi, Soheil and A. Roll},
title = {Interdependence of Primary and Johari−Goldstein Secondary Relaxations in Glass-Forming Systems},
journal = {Journal of Physical Chemistry B},
year = {2008},
volume = {112},
number = {15},
month = {April},
issn = {1520-6106},
pages = {4470--4473},
numpages = {3},
keywords = {glass transition},
}

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%0 Journal Article
%T Interdependence of Primary and Johari−Goldstein Secondary Relaxations in Glass-Forming Systems
%A K. Kessair
%A Capaccio
%A D. Prevost
%A M. Lucche
%A SHarifi, Soheil
%A A. Roll
%J Journal of Physical Chemistry B
%@ 1520-6106
%D 2008

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