Catalysis Letters, ( ISI ), Volume (147), No (2), Year (2017-2) , Pages (360-373)

Title : ( Aminophosphine Palladium(0) Complex Supported on ZrO2 Nanoparticles (ZrO2@AEPH2-PPh2-Pd(0)) as an Efficient Heterogeneous Catalyst for Suzuki–Miyaura and Heck–Mizoroki Reactions in Green Media )

Authors: seyede nasrin razavi , Batool Akhlaghinia , Roya Jahanshahi ,

Citation: BibTeX | EndNote

Abstract

A new aminophosphine palladium(0) complex supported on ZrO2 nanoparticles (ZrO2@AEPH2-PPh2- Pd(0)) was successfully synthesized and characterized using FT-IR, XRD, XPS, SEM, TEM, EDS, TGA and ICP techniques. Characterization results revealed that the synthesized catalyst had tetragonal and monoclinic structurewith spherical morphology. The prepared nanocatalyst was showed excellent reactivity in the Suzuki–Miyaura and Heck–Mizoroki cross-coupling reactions. Moreover, this nanocatalyst can be easily recovered and reused for at least six cycles without deterioration in catalytic activity.

Keywords

, N-phosphine palladium complex (ZrO2@AEPH2-PPh2-Pd), Heck–Mizoroki reaction; Suzuki–Miyaura reaction, heterogeneous catalyst, ZrO2, aryl halides.
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@article{paperid:1060531,
author = {Razavi, Seyede Nasrin and Akhlaghinia, Batool and Jahanshahi, Roya},
title = {Aminophosphine Palladium(0) Complex Supported on ZrO2 Nanoparticles (ZrO2@AEPH2-PPh2-Pd(0)) as an Efficient Heterogeneous Catalyst for Suzuki–Miyaura and Heck–Mizoroki Reactions in Green Media},
journal = {Catalysis Letters},
year = {2017},
volume = {147},
number = {2},
month = {February},
issn = {1011-372X},
pages = {360--373},
numpages = {13},
keywords = {N-phosphine palladium complex (ZrO2@AEPH2-PPh2-Pd); Heck–Mizoroki reaction; Suzuki–Miyaura reaction; heterogeneous catalyst; ZrO2; aryl halides.},
}

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%0 Journal Article
%T Aminophosphine Palladium(0) Complex Supported on ZrO2 Nanoparticles (ZrO2@AEPH2-PPh2-Pd(0)) as an Efficient Heterogeneous Catalyst for Suzuki–Miyaura and Heck–Mizoroki Reactions in Green Media
%A Razavi, Seyede Nasrin
%A Akhlaghinia, Batool
%A Jahanshahi, Roya
%J Catalysis Letters
%@ 1011-372X
%D 2017

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