Title : ( The Structural Study of [2-Cl-C6H4C(O)NH]P(O)[NHC6H4-4-CH3]2 )
Authors: Maryam Taherzadeh , Mehrdad Pourayoubi , M. Dusek , M. Kucerakova ,
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Abstract
A new phosphoric triamide with the formula [2-Cl-C6H4C(O)NH]P(O)[NHC6H4-4-CH3]2 has been investigated by spectroscopic methods and X-ray crystallography. This compound crystallizes in the monoclinic system, with P21/c space group. In this molecule, the P atom has a distorted tetrahedral environment. The N atoms bonded to P atom have mainly sp2 character. In the crystal, the molecules are aggregated through NCP―H…O═P and NP―H…O═C hydrogen bonds in a linear arrangement along the b axis, by forming a sequence of alternate R22(8) and R22(12) motifs (NCP is the nitrogen atom of C(O)NHP(O) segment and the NP stands the two other nitrogen atoms bonded to the P atom). Furthermore, C―H…O and C―H…Cl intermolecular interactions complete a 3D structure.
Keywords
, Phosphoric triamide, Hydrogen bond, Crystal structure, Graph set motif
@article{paperid:1062703,
author = {Taherzadeh, Maryam and Pourayoubi, Mehrdad and M. Dusek and M. Kucerakova},
title = {The Structural Study of [2-Cl-C6H4C(O)NH]P(O)[NHC6H4-4-CH3]2},
journal = {Structural Chemistry and Crystallography Communication},
year = {2016},
volume = {2},
number = {2},
month = {November},
issn = {2470-9905},
pages = {1--5},
numpages = {4},
keywords = {Phosphoric triamide; Hydrogen bond; Crystal structure; Graph set motif},
}
%0 Journal Article
%T The Structural Study of [2-Cl-C6H4C(O)NH]P(O)[NHC6H4-4-CH3]2
%A Taherzadeh, Maryam
%A Pourayoubi, Mehrdad
%A M. Dusek
%A M. Kucerakova
%J Structural Chemistry and Crystallography Communication
%@ 2470-9905
%D 2016
