هجدهمین کنفرانس شیمی معدنی ایران , 2017-03-07

Title : ( Copper(II) complex by 1,10-phenanthroline and Salicylaldehyde S-benzylisothiosemicarbazone hydrogen chloride: Synthesis, characterization and crystal structure )

Authors: milad mahjoobizadeh , Reza Takjoo ,

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Abstract

Mixed-ligand Cu(II) complex with general formula of [Cu(Phen)2Cl].H2L,Cl,H2O (Figure) is prepared by reaction of Cu(OAc)2.H2O, 1,10-phenanthroline and salicylaldehyde S-benzylisothiosemicarbazone.hydrogenchloride (H2L) in a 1:2:1 mol ratio. Its structure is characterized by elemental, IR and single crystal X-ray diffraction analyses which are precisely used to better understand the molecular structure of the complex. Coordination geometry around the central atom in the Cu(II) complex, is a distorted square-pyramidal. Two 1,10-phenanthroline ligands (NN donor) are coordinated to the central metal as bidentate neutral agents and the last position is occupied by the chlorine atom. Moreover, there are one salicylaldehyde S-benzylisothiosemicarbazone free ligand, a water molecule and a chlorine atom in the crystal lattice.

Keywords

, Schiff base, Cu(II) complex, 1, 10-phenanthroline
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@inproceedings{paperid:1063915,
author = {Mahjoobizadeh, Milad and Takjoo, Reza},
title = {Copper(II) complex by 1,10-phenanthroline and Salicylaldehyde S-benzylisothiosemicarbazone hydrogen chloride: Synthesis, characterization and crystal structure},
booktitle = {هجدهمین کنفرانس شیمی معدنی ایران},
year = {2017},
location = {مشهد, IRAN},
keywords = {Schiff base; Cu(II) complex; 1;10-phenanthroline},
}

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%0 Conference Proceedings
%T Copper(II) complex by 1,10-phenanthroline and Salicylaldehyde S-benzylisothiosemicarbazone hydrogen chloride: Synthesis, characterization and crystal structure
%A Mahjoobizadeh, Milad
%A Takjoo, Reza
%J هجدهمین کنفرانس شیمی معدنی ایران
%D 2017

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