Title : ( Synthesis and Single Crystal Structure Description of Two New Polyoxometalate–Melamine Hybrids )
Authors: Abolghasem Farhadipour , Hossein Eshghi , Mozhde Yousefi Hasan Abadi , B. Artetxe ,
دانلود فایل برای اعضای دانشگاهAccess to full-text not allowed by authors
Abstract
Abstract Two new organic–inorganic hybrid compounds based on Keggin-type polyoxometalates and melaminium cations, namely (C3N6H7)3[PW12O40]·6H2O (1) and (C3N6H7)4[SiW12O40]·6H2O (2) have been synthesized at room temperature by a solvent diffusion method and characterized by IR spectroscopy, CHN analyses and single-crystal X-ray diffraction. Hybrid 1 consists of three melamonium cations per [ PW12O40]3− unit with the hydration water molecules connected to each other via hydrogen bonding forming a 1D zigzag chain. In compound 2,[SiW12O40]4− polyanions and water molecules act as inorganic layers that are alternating with layers of monoprotonated organic melaminium cations.
Keywords
Solvent diffusion method · Polyoxometalates · Organic–inorganic hybrids · Melamine
@article{paperid:1064641,
author = {Farhadipour, Abolghasem and Eshghi, Hossein and Yousefi Hasan Abadi, Mozhde and B. Artetxe},
title = {Synthesis and Single Crystal Structure Description of Two New Polyoxometalate–Melamine Hybrids},
journal = {Journal of Chemical Crystallography},
year = {2017},
volume = {47},
number = {5},
month = {July},
issn = {1074-1542},
pages = {140--150},
numpages = {10},
keywords = {Solvent diffusion method · Polyoxometalates · Organic–inorganic hybrids · Melamine},
}
%0 Journal Article
%T Synthesis and Single Crystal Structure Description of Two New Polyoxometalate–Melamine Hybrids
%A Farhadipour, Abolghasem
%A Eshghi, Hossein
%A Yousefi Hasan Abadi, Mozhde
%A B. Artetxe
%J Journal of Chemical Crystallography
%@ 1074-1542
%D 2017
