Applied Organometallic Chemistry, Volume (32), No (2), Year (2018-2) , Pages (1-12)

Title : ( Cu(II) immobilized on guanidinated epibromohydrinfunctionalized γ‐Fe2O3@TiO2 (γ‐Fe2O3@TiO2 ‐EG‐Cu(II)): A highly efficient magnetically separable heterogeneous nanocatalyst for one‐pot synthesis of highly substituted imidazoles )

Authors: mahdi nejatianfar , Batool Akhlaghinia , Roya Jahanshahi ,

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Abstract

A simple, efficient and eco‐friendly procedure has been developed using Cu(II) immobilized on guanidinated epibromohydrin‐functionalized γ‐Fe2O3@TiO2 (γ‐Fe2O3@TiO2 ‐EG‐Cu(II)) for the synthesis of 2,4,5‐trisubstituted and 1,2,4,5‐ tetrasubstituted imidazoles, via the condensation reactions of various aldehydes with benzil and ammonium acetate or ammonium acetate and amines, under solvent‐ free conditions. High‐resolution transmission electron microscopy analysis of this catalyst clearly affirmed the formation of a γ‐Fe2O3 core and a TiO2 shell, with mean sizes of about 10–20 and 5–10 nm, respectively. These data were in very good agreement with X‐ray crystallographic measurements (13 and 7 nm). Moreover, magnetization measurements revealed that both γ‐Fe2O3@TiO2 and γ‐Fe2O3@TiO2 ‐EG‐Cu(II) had superparamagnetic behaviour with saturation magnetization of 23.79 and 22.12 emu g−1, respectively. γ‐Fe2O3@TiO2 ‐EGCu( II) was found to be a green and highly efficient nanocatalyst, which could be easily handled, recovered and reused several times without significant loss of its activity. The scope of the presented methodology is quite broad; a variety of aldehydes as well as amines have been shown to be viable substrates. A mechanism for the cyclocondensation reaction has also been proposed.

Keywords

, Cu(II) immobilized on guanidinated epibromohydrin‐functionalized γ‐Fe2O3@TiO2 (γ‐Fe2O3@TiO2 ‐ EG‐Cu(II)), heterogeneous nanocatalyst, solvent‐free, substituted imidazoles
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@article{paperid:1064938,
author = {Nejatianfar, Mahdi and Akhlaghinia, Batool and Jahanshahi, Roya},
title = {Cu(II) immobilized on guanidinated epibromohydrinfunctionalized γ‐Fe2O3@TiO2 (γ‐Fe2O3@TiO2 ‐EG‐Cu(II)): A highly efficient magnetically separable heterogeneous nanocatalyst for one‐pot synthesis of highly substituted imidazoles},
journal = {Applied Organometallic Chemistry},
year = {2018},
volume = {32},
number = {2},
month = {February},
issn = {0268-2605},
pages = {1--12},
numpages = {11},
keywords = {Cu(II) immobilized on guanidinated epibromohydrin‐functionalized γ‐Fe2O3@TiO2 (γ‐Fe2O3@TiO2 ‐ EG‐Cu(II)); heterogeneous nanocatalyst; solvent‐free; substituted imidazoles},
}

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%0 Journal Article
%T Cu(II) immobilized on guanidinated epibromohydrinfunctionalized γ‐Fe2O3@TiO2 (γ‐Fe2O3@TiO2 ‐EG‐Cu(II)): A highly efficient magnetically separable heterogeneous nanocatalyst for one‐pot synthesis of highly substituted imidazoles
%A Nejatianfar, Mahdi
%A Akhlaghinia, Batool
%A Jahanshahi, Roya
%J Applied Organometallic Chemistry
%@ 0268-2605
%D 2018

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