Title : ( Syntheses and characterization of two new coordination compounds containing an azide ligand in the presence of o‐donor co‐ligands with nickel and copper(II) metal ions and an investigation into the effects of sonochemical methods on morphology and particle size )
Authors: azam hassanpoor , Masoud Mirzaei Shahrabi , Hossein Eshtiagh Hosseini ,
Full TextAbstract
In this research, two new coordination complexes {[Ni(but-1,4-dc)0.5(N3)(H2O)]·3H2O}n (1) and {[Cu(bpc)(N3)(H2O)]·H2O}n (2) were synthesized from butane-1,4-dicarboxylate (but-1,4-dc) or benzophenone-2-carboxylate (bpc) and N3– ligands. Further, the effectiveness of sonochemistry synthesis for the preparation of nanosheets of these compounds and the effect of particle size on thermal stability were investigated. The nanoparticles were characterized by scanning electron microscopy (SEM), elemental analysis, powder X-ray diffraction (PXRD), infrared spectroscopy (IR), and thermogravimetric (TGA) analysis.
Keywords
, coordination complex, Azido ligand, Sonochemistry, Nano-sheets.
@article{paperid:1067348,
author = {Hassanpoor, Azam and Mirzaei Shahrabi, Masoud and Eshtiagh Hosseini, Hossein},
title = {Syntheses and characterization of two new coordination compounds containing an azide ligand in the presence of o‐donor co‐ligands with nickel and copper(II) metal ions and an investigation into the effects of sonochemical methods on morphology and particle size},
journal = {Journal of the Iranian Chemical Society},
year = {2018},
volume = {15},
number = {6},
month = {May},
issn = {1735-207X},
pages = {1287--1292},
numpages = {5},
keywords = {coordination complex; Azido ligand; Sonochemistry; Nano-sheets.},
}
%0 Journal Article
%T Syntheses and characterization of two new coordination compounds containing an azide ligand in the presence of o‐donor co‐ligands with nickel and copper(II) metal ions and an investigation into the effects of sonochemical methods on morphology and particle size
%A Hassanpoor, Azam
%A Mirzaei Shahrabi, Masoud
%A Eshtiagh Hosseini, Hossein
%J Journal of the Iranian Chemical Society
%@ 1735-207X
%D 2018
