Title : ( An eight-coordinate zinc complex containing the highly pre-organized ligand 1,10-phenanthroline-2,9-dicarboxylic acid: Solvothermal synthesis, supramolecular structure and CSD studies )
Authors: Masoud Mirzaei Shahrabi , azam hassanpoor , haniyeh alizadeh , mahnaz gohari , A. J. Blake ,
Full TextAbstract
A new anionic coordination complex of Zn(II) containing the highly pre-organized ligand 1,10-phenanthroline-2,9-dicarboxylate (PDA), (H3O)2[Zn(PDA)2]·2CH3NO2·2H2O·(1), has been synthesized by solvothermal methods and characterised by elemental analysis, infrared spectroscopy and single-crystal X-ray diffraction. The last of these techniques revealed a coordination sphere around Zn(II) consisting of four N atoms and four O donors from two 1,10-phenanthroline-2,9-dicarboxylate ligands which features a distorted dodecahedral geometry. The ionic coordination motifs in 1 are held together by intermolecular O−H···O, N−H···O and C−H···O hydrogen bonding, C−H···π and π−π stacking interactions, to produce an extended 2D architecture.
Keywords
, pre-organized ligand; 1, 10-phenanthroline-2, 9-dicarboxylic acid; zinc complex; π−π stacking interaction; hydrogen bonding.
@article{paperid:1068953,
author = {Mirzaei Shahrabi, Masoud and Hassanpoor, Azam and Alizadeh, Haniyeh and Gohari, Mahnaz and A. J. Blake},
title = {An eight-coordinate zinc complex containing the highly pre-organized ligand 1,10-phenanthroline-2,9-dicarboxylic acid: Solvothermal synthesis, supramolecular structure and CSD studies},
journal = {Journal of Molecular Structure},
year = {2018},
volume = {1171},
number = {1171},
month = {July},
issn = {0022-2860},
pages = {626--630},
numpages = {4},
keywords = {pre-organized ligand; 1;10-phenanthroline-2;9-dicarboxylic acid; zinc complex;
π−π stacking interaction; hydrogen bonding.},
}
%0 Journal Article
%T An eight-coordinate zinc complex containing the highly pre-organized ligand 1,10-phenanthroline-2,9-dicarboxylic acid: Solvothermal synthesis, supramolecular structure and CSD studies
%A Mirzaei Shahrabi, Masoud
%A Hassanpoor, Azam
%A Alizadeh, Haniyeh
%A Gohari, Mahnaz
%A A. J. Blake
%J Journal of Molecular Structure
%@ 0022-2860
%D 2018
