Title : ( Metal-Free Debromination of 5-Bromopyrimidine Derivatives Using DMF/Trialkylamine as the Hydrogen Source )
Authors: Mahsa Mousavi , Mehdi Bakavoli , Ali Shiri , javad tajabadi ,
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Abstract
Attempted heterocyclization of 5-bromo-2,4-diamino-6-substituted pyrimidines in a mixture of DMF and trialkylamines (Et3N or N,N-diisopropylethylamine) under mild conditions, led to the formation of new dehalogenated derivatives as the main product. This metal-free catalyzed debromination process presents DMF/R3N combination as a potential metal-free reductive system.
Keywords
, Metal-Free Debromination, 5-Bromopyrimidine, Hydrogen Source
@article{paperid:1069036,
author = {Mousavi, Mahsa and Bakavoli, Mehdi and Shiri, Ali and Tajabadi, Javad},
title = {Metal-Free Debromination of 5-Bromopyrimidine Derivatives Using DMF/Trialkylamine as the Hydrogen Source},
journal = {ChemistrySelect},
year = {2018},
volume = {3},
number = {19},
month = {May},
issn = {2365-6549},
pages = {5401--5404},
numpages = {3},
keywords = {Metal-Free Debromination; 5-Bromopyrimidine; Hydrogen Source},
}
%0 Journal Article
%T Metal-Free Debromination of 5-Bromopyrimidine Derivatives Using DMF/Trialkylamine as the Hydrogen Source
%A Mousavi, Mahsa
%A Bakavoli, Mehdi
%A Shiri, Ali
%A Tajabadi, Javad
%J ChemistrySelect
%@ 2365-6549
%D 2018
