Title : ( Photochemical and electrochemical hydrogen evolution reactivity of lanthanide-functionalized polyoxotungstates )
Authors: marzieh arab fashapoyeh , Masoud Mirzaei Shahrabi , Hossein Eshtiagh Hosseini , A. Rajagopal , M. Lechner , R. Liu , C. Streb ,
Full TextAbstract
The first example of hydrogen evolution reactivity (HER) of lanthanide-functionalized Keggin-based polyoxotungstates under photochemical and electrochemical conditions is reported. The HER activity under homogeneous, visible light-driven conditions and under heterogeneous, electrochemical conditions depends on the type of lanthanide functionalization, so that a new class of model HER catalysts for systematic reactivity studies is now accessible.
Keywords
, Polyoxometalates; Lanthanide, functionalized polyoxotungstates; Lacunary polyoxotungstates; Photochemistry; Electrochemistry; Hydrogen evolution reactivity.
@article{paperid:1069747,
author = {Arab Fashapoyeh, Marzieh and Mirzaei Shahrabi, Masoud and Eshtiagh Hosseini, Hossein and A. Rajagopal and M. Lechner and R. Liu and C. Streb},
title = {Photochemical and electrochemical hydrogen evolution reactivity of lanthanide-functionalized polyoxotungstates},
journal = {Chemical Communications},
year = {2018},
volume = {54},
number = {74},
month = {September},
issn = {1359-7345},
pages = {10427--10430},
numpages = {3},
keywords = {Polyoxometalates; Lanthanide-functionalized polyoxotungstates; Lacunary polyoxotungstates; Photochemistry; Electrochemistry; Hydrogen evolution reactivity.},
}
%0 Journal Article
%T Photochemical and electrochemical hydrogen evolution reactivity of lanthanide-functionalized polyoxotungstates
%A Arab Fashapoyeh, Marzieh
%A Mirzaei Shahrabi, Masoud
%A Eshtiagh Hosseini, Hossein
%A A. Rajagopal
%A M. Lechner
%A R. Liu
%A C. Streb
%J Chemical Communications
%@ 1359-7345
%D 2018
