Title : ( Bromination of phenol and anillin derivatives in presence of MdPd( Br3)2 )
Authors: Mohammad Izadi Gonabadi , Mostafa Gholizadeh ,
Full TextAbstract
Mono(6,7-dihydrodipyrido[1,2-a:2',1'-c]pyrazine-5,8-diium)hexabromide[MdPd].(Br3)2was quantitatively prepared and used for the bromination of anilines and phenols in the presence of a mixed solvent system (e.g., Acetonitril or DCM/MeOH 2:1) and under solvent free conditions [1-2].Also it has been done selective oxidation of Benzyl alcohols to their corresponding carbonyl compounds in presence of Mono (6,7-dihydrodipyrido[1,2-a:2',1'-c]pyrazine-5,8-diium) diperchlorate.This new ionic liquid has advantages over similar brominating agents in terms of short reaction time, simple workup, regioselectivity and high yields.
Keywords
, Bromination, Phenol, Anillin
@inproceedings{paperid:1070049,
author = {Izadi Gonabadi, Mohammad and Gholizadeh, Mostafa},
title = {Bromination of phenol and anillin derivatives in presence of MdPd( Br3)2},
booktitle = {20th Iranian Chemistry Congress},
year = {2018},
location = {مشهد, IRAN},
keywords = {Bromination; Phenol; Anillin},
}
%0 Conference Proceedings
%T Bromination of phenol and anillin derivatives in presence of MdPd( Br3)2
%A Izadi Gonabadi, Mohammad
%A Gholizadeh, Mostafa
%J 20th Iranian Chemistry Congress
%D 2018
