Title : ( Crystal structure and Hirshfeld surface analysis of 1,2-Ethylene-bis -para-methyl pyridinium- dichromate as a new selective and mild agent in oxidation of alcohols )
Authors: Mostafa Gholizadeh , Mehrdad Pourayoubi , Mohammad Reza Housaindokht , H. AMIRI RUDBARI , masumeh farimaneh , Anahid Saneei , Giuseppe BRUNO ,
Full TextAbstract
1,2-Ethylene-bis-para-methyl pyridinium- dichromate, -C14H18N2-[Cr2O7], is used as a new oxidizing agent in conversion of some alcohols to their corresponding carbonyl compounds in CH3CN solvent and also under solvent-free conditions. In both procedures, high conversion percentages are observed. However, a much shorter reaction time is achieved in solvent-free conditions. For allylic alcohols, the C═C double bond is not oxidized and the examined saturated alcohol in this work -i.e. cyclo-hexanol- remains intact which represents the mild nature of reagent used. The structure of reagent is investigated by single crystal X-ray diffraction analysis. The C–H···O and O···π interactions are the most important features of crystal packing, which is visualized by the Hirshfeld surface map.
Keywords
, Alcohol oxidation, 1, 2-ethylene-bis-para-methyl pyridinium- dichromate, Hirshfeld surface analysis, solvent-free condition, X-ray crystallography
@article{paperid:1071048,
author = {Gholizadeh, Mostafa and Pourayoubi, Mehrdad and Housaindokht, Mohammad Reza and H. AMIRI RUDBARI and Farimaneh, Masumeh and Saneei, Anahid and Giuseppe BRUNO},
title = {Crystal structure and Hirshfeld surface analysis of 1,2-Ethylene-bis -para-methyl pyridinium- dichromate as a new selective and mild agent in oxidation of alcohols},
journal = {Turkish Journal of Chemistry},
year = {2019},
volume = {43},
number = {1},
month = {February},
issn = {1300-0527},
pages = {185--196},
numpages = {11},
keywords = {Alcohol oxidation; 1;2-ethylene-bis-para-methyl pyridinium- dichromate; Hirshfeld surface analysis; solvent-free condition; X-ray crystallography},
}
%0 Journal Article
%T Crystal structure and Hirshfeld surface analysis of 1,2-Ethylene-bis -para-methyl pyridinium- dichromate as a new selective and mild agent in oxidation of alcohols
%A Gholizadeh, Mostafa
%A Pourayoubi, Mehrdad
%A Housaindokht, Mohammad Reza
%A H. AMIRI RUDBARI
%A Farimaneh, Masumeh
%A Saneei, Anahid
%A Giuseppe BRUNO
%J Turkish Journal of Chemistry
%@ 1300-0527
%D 2019
