A porous poly (ethylene-chlorotrifluoroethylene) (ECTFE) membrane was prepared and evaluated in this study. Initially, solvent screening revealed diethyl phthalate (DEP) and glycerol triacetate (GTA) as proper solvents for the preparation of homogenous ECTFE solutions with the required properties for fabricating a hollow fiber membrane. The thermodynamic phase diagrams for both systems (ECTFE/DEP and ECTFE/GTA) showed a liquid–liquid (L-L) phase separation region, which is needed for a bicontinuous structure, prior to solid–liquid (S-L) phase separation (polymer crystallization). The ECTFE hollow fiber membranes were prepared by a thermally induced phase separation (TIPS) method using a unary solvent (DEP or GTA). The morphologies of hollow fiber membranes were observed by scanning electron microscopy (SEM) and it was observed that a bicontinuous structure was formed through L-L phase separation. The effect of the solvent types on properties of the prepared membrane such as water permeability and mechanical strength was discussed in detail. Moreover, the spherulite growth rate and crystallization degree were measured to assess the differences in the mechanical properties of the membranes prepared using DEP and GTA. In this study, with a polymer concentration of 20 wt%, the membrane showed a superior water flux and comparable mechanical properties with the ECTFE membranes already reported in published papers. Furthermore, the chemical resistance properties of ECTFE hollow fiber membranes were evaluated using the harsh treatments.

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