Title : ( Dicyclohexylammonium O,O’-Diphenyl Phosphate, [(C6H11)2NH2][(C6H5O)2P(O)(O)]: Spectroscopic Study, Crystal Structure, and Hirshfeld Surface Analysis )
Authors: Samira Nazari Moghaddam , Akbar Raissi Shabari , Fahimeh Sabbaghi , Mehrdad Pourayoubi , Abdul Ajees Abdul Salam ,
Full TextAbstract
The title salt, [-C6H11-2NH2][-C6H5O-2P-O--O-], crystallizes in the chiral space group P212121, composed of achiral cation and anion components. The strong charge-assisted N–H...O hydrogen bonds build a linear assembly along the a axis, including a non-centrosymmetric C22-6- chain graph-set motif. The intra and intermolecular C–H...O interactions as well as the C–H...π-electron ring interactions also exist in the crystal structure. Fingerprint plots are used for a detailed investigation of intermolecular interactions participating in the crystal packing. The spectroscopic features -IR, 1H NMR, 13C{1H} NMR, 31P{1H} NMR, and mass- are studied.
Keywords
, phosphate; X, ray structure analysis; chiral space group; charge, assisted hydrogen bond; NMR
@article{paperid:1074079,
author = {Samira Nazari Moghaddam and Akbar Raissi Shabari and Fahimeh Sabbaghi and Pourayoubi, Mehrdad and Abdul Ajees Abdul Salam},
title = {Dicyclohexylammonium O,O’-Diphenyl Phosphate, [(C6H11)2NH2][(C6H5O)2P(O)(O)]: Spectroscopic Study, Crystal Structure, and Hirshfeld Surface Analysis},
journal = {Molbank},
year = {2019},
volume = {2019},
number = {1},
month = {March},
issn = {1422-8599},
keywords = {phosphate; X-ray structure analysis; chiral space group; charge-assisted hydrogen bond; NMR},
}
%0 Journal Article
%T Dicyclohexylammonium O,O’-Diphenyl Phosphate, [(C6H11)2NH2][(C6H5O)2P(O)(O)]: Spectroscopic Study, Crystal Structure, and Hirshfeld Surface Analysis
%A Samira Nazari Moghaddam
%A Akbar Raissi Shabari
%A Fahimeh Sabbaghi
%A Pourayoubi, Mehrdad
%A Abdul Ajees Abdul Salam
%J Molbank
%@ 1422-8599
%D 2019
