Revue Roumaine de Chimie, Volume (64), No (3), Year (2019-3) , Pages (209-215)

Title : ( SYNTHESIS, SPECTROSCOPIC CHARACTERIZATION, CRYSTAL STRUCTURE AND HIRSHFELD SURFACE ANALYSIS OF (4-Cl-C6H4O)(OC4H8N)2PO AMIDOPHOSPHOESTER )

Authors: Samira Nazari Moghaddam , Akbar Raissi Shabari , Fahimeh Sabbaghi , Mehrdad Pourayoubi ,

Citation: BibTeX | EndNote

Abstract

A new amidophosphoester, (4-Cl-C6H4O)(OC4H8N)2PO, was synthesized and characterized by spectroscopic methods (IR, 31P-, 13C-, 1H-NMR) and single-crystal X-ray diffraction. The crystal belongs to the space group P21/c, and the asymmetric unit of structure is composed of one complete molecule. The P atom has a distorted tetrahedral (O)(N)2P(O) environment with one of the O═P—N angles as the maximum angle at the P atom and one of the O—P—N angles as the minimum angle. The oxygen atom of the P—O—C6H4-4-Cl part may be ascribed with the hybridization including a few more “s” character with respect to “sp2”, reflected in the P—O—C angle (127°). In the crystal, the molecules are aggregated through CH…O hydrogen bonds forming a two-dimensional array along the bc plane.

Keywords

, Amidophosphoester, X-Ray Crystallography, Hirshfeld Surface Analysis
برای دانلود از شناسه و رمز عبور پرتال پویا استفاده کنید.

@article{paperid:1075455,
author = {سمیرا نظری مقدم and اکبر رئیسی شبری and فهیمه صباغی and Pourayoubi, Mehrdad},
title = {SYNTHESIS, SPECTROSCOPIC CHARACTERIZATION, CRYSTAL STRUCTURE AND HIRSHFELD SURFACE ANALYSIS OF (4-Cl-C6H4O)(OC4H8N)2PO AMIDOPHOSPHOESTER},
journal = {Revue Roumaine de Chimie},
year = {2019},
volume = {64},
number = {3},
month = {March},
issn = {0035-3930},
pages = {209--215},
numpages = {6},
keywords = {Amidophosphoester; X-Ray Crystallography; Hirshfeld Surface Analysis},
}

[Download]

%0 Journal Article
%T SYNTHESIS, SPECTROSCOPIC CHARACTERIZATION, CRYSTAL STRUCTURE AND HIRSHFELD SURFACE ANALYSIS OF (4-Cl-C6H4O)(OC4H8N)2PO AMIDOPHOSPHOESTER
%A سمیرا نظری مقدم
%A اکبر رئیسی شبری
%A فهیمه صباغی
%A Pourayoubi, Mehrdad
%J Revue Roumaine de Chimie
%@ 0035-3930
%D 2019

[Download]