Title : ( PdII Immobilized on Ferromagnetic Multi-Walled Carbon Nanotubes Functionalized by Aminated 2-Chloroethylphosphonic Acid with S-Methylisothiourea (FMMWCNTs@CPA@SMTU@PdII NPs) Applied as a Highly Efficient and Recyclable Nanostructured Catalyst for Suzuki–Miyaura and Mizoroki–Heck Cross-Coupling Reactions in Solvent-Free Conditions )
Authors: maryam sadat ghasemzadeh , Batool Akhlaghinia ,
Full TextAbstract
The new ferromagnetic nanostructured FMMWCNTs@CPA@SMTU@PdII NPs (IV) as an eco-friendly heterogeneous nanocatalyst with a particle size of ,20–30nm reported earlier by our group has been found to be very effective for Suzuki–Miyaura and Mizoroki–Heck cross-coupling reactions at ambient temperature. The procedure has been applied for a wide range of aryl halides, arylboronic acids, and alkenes. The magnetic separation by an external magnetic field, mild reaction conditions, and catalyst reusability up to four times without significant decrease in catalytic activity (reduced catalytic activity from 11 to 18% in the fifth, sixth, and seventh cycles) made the present method sustainable and economically viable for C–C cross-coupling reactions.
Keywords
, FMMWCNTs@CPA@SMTU@PdII NPs (IV), Heterogeneous nanostructured catalyst, Suzuki-Miyaura, Mizoroki-Heck, Green chemistry
@article{paperid:1075993,
author = {Ghasemzadeh, Maryam Sadat and Akhlaghinia, Batool},
title = {PdII Immobilized on Ferromagnetic Multi-Walled Carbon Nanotubes Functionalized by Aminated 2-Chloroethylphosphonic Acid with S-Methylisothiourea (FMMWCNTs@CPA@SMTU@PdII NPs) Applied as a Highly Efficient and Recyclable Nanostructured Catalyst for Suzuki–Miyaura and Mizoroki–Heck Cross-Coupling Reactions in Solvent-Free Conditions},
journal = {Australian Journal of Chemistry},
year = {2019},
volume = {72},
number = {9},
month = {January},
issn = {0004-9425},
pages = {674--692},
numpages = {18},
keywords = {FMMWCNTs@CPA@SMTU@PdII NPs (IV); Heterogeneous nanostructured catalyst; Suzuki-Miyaura; Mizoroki-Heck; Green chemistry},
}
%0 Journal Article
%T PdII Immobilized on Ferromagnetic Multi-Walled Carbon Nanotubes Functionalized by Aminated 2-Chloroethylphosphonic Acid with S-Methylisothiourea (FMMWCNTs@CPA@SMTU@PdII NPs) Applied as a Highly Efficient and Recyclable Nanostructured Catalyst for Suzuki–Miyaura and Mizoroki–Heck Cross-Coupling Reactions in Solvent-Free Conditions
%A Ghasemzadeh, Maryam Sadat
%A Akhlaghinia, Batool
%J Australian Journal of Chemistry
%@ 0004-9425
%D 2019
