Title : ( Synthesis and Crystal Structure of [Benzyl N'-[[2-(hydroxy-kO)phenyl]ethylene]-N-[[2-(hydroxy-kO)phenyl]methylene]-carbamohydrazonothioato-kN,kN']-ethanol-dioxido-uranium )
Authors: Reza Takjoo , J. T. Mague ,
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Abstract
The uranyl compound UO2(L\\\')EtOH (L\\\' = benzyl N-(2-(oxidanyl)benzylidene)-N\\\'-((2-(1-oxidanyl) phenyl)ethylidene) carbamohydrazonothioate) was synthesized and its molecular and crystal structure was determined by X-ray diffraction. The compound crystallizes in the triclinic sp. gr. P , Z = 2. The coordination geometry about the uranium atom is distorted pentagonal bipyramidal consisting of a UO2O4N2 polyhedron where the oxido ligands occupy axial positions with a symmetric linear structure (O=U=O angle = 179.11(12)°). The pentagonal plane (N2O3) is formed by the dinegative, tetradentate Schiff base ligand (N2O2) and the oxygen atom of the coordinated alcohol ligand. In the complex, the ligand adopts a propeller-like conformation.
Keywords
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@article{paperid:1079380,
author = {Takjoo, Reza and جول مگ},
title = {Synthesis and Crystal Structure of [Benzyl N'-[[2-(hydroxy-kO)phenyl]ethylene]-N-[[2-(hydroxy-kO)phenyl]methylene]-carbamohydrazonothioato-kN,kN']-ethanol-dioxido-uranium},
journal = {Crystallography Reports},
year = {2019},
volume = {64},
number = {7},
month = {December},
issn = {1063-7745},
pages = {1089--1093},
numpages = {4},
keywords = {-},
}
%0 Journal Article
%T Synthesis and Crystal Structure of [Benzyl N'-[[2-(hydroxy-kO)phenyl]ethylene]-N-[[2-(hydroxy-kO)phenyl]methylene]-carbamohydrazonothioato-kN,kN']-ethanol-dioxido-uranium
%A Takjoo, Reza
%A جول مگ
%J Crystallography Reports
%@ 1063-7745
%D 2019
