RSC Advances, ( ISI ), Volume (10), No (26), Year (2020-1) , Pages (15044-15051)
Title : ( A new class of organoplatinum-based DFNS for the production of cyclic carbonates from olefins and CO2 )
Authors: Maryam Abassian , Rahele Zhiani , Alireza Motavalizadehkakhky , Hossein Eshghi , Jamshid Mehrzad ,Access to full-text not allowed by authors
Abstract
We studied the potential application of an efficient, reusable, and easily recoverable catalyst of dendritic fibrous nanosilica (DFNS)-supported platinum(II) complexes (DFNS/Pt(II) NPs) to form cyclic carbonates in the presence of epoxides by converting carbon dioxide. Cyclic carbonates from epoxides and carbon dioxide is proposed as the most appropriate way to synthesis this C1 building block. We performed FESEM, TEM, TGA, BET, VSM, and ICP-MS to thoroughly characterize DFNS/Pt(II) NPs.