Title : ( Separation/Competitive Transport of Heavy Metal Ions across the Bulk Liquid Membranes with N,N',N''-Tris(4-methylphenyl)phosphoric Triamide As Carrier )
Authors: Setareh Akbari , Razieh Sanavi Khoshnood , Mehrdad Pourayoubi ,
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Abstract
The competitive bulk liquid membrane transport of seven metal ion by N,N\\\',N\\\"-tris(4-methylphenyl)phosphoric triamide carrier was studied using a flame atomic absorption spectrometry. Dichloromethane (DCM), chloroform (CHCl3), nitrobenzene (NB) and 1,2-dichloroethane (1,2-DCE) solvents have been used as bulk liquid membranes (BLM). The carrier has been shown the maximum transport rate for Cu2+ cation in all of the BLM systems (except of 1,2-DCE) in comparison to the other cations containing Co2+, Cd2+, Ag+, Pb2+, Ni2+, Cu2+, and Zn2+. The obtained results show that the selectivity and efficiency of transport in presence of this ligand change with the type of organic solvents. Various factors that affect the transport efficiency of this heavy metal cations have been optimized in order to obtain maximum transport. The complexation process between phosphoric triamide and Cu2+ cation have also been examined by conductometry method. The stoichiometry of the complex and the formation constant of phosphoric triamide-Cu2+ complex have been determined.
Keywords
, competitive transport, N, N\', N\"-tris(4-methylphenyl)phosphoric triamide carrier, Cu2+ ion, bulk liquid membrane
@article{paperid:1079796,
author = {ستاره اکبری and راضیه ثانوی خشنود and Pourayoubi, Mehrdad},
title = {Separation/Competitive Transport of Heavy Metal Ions across the Bulk Liquid Membranes with N,N',N''-Tris(4-methylphenyl)phosphoric Triamide As Carrier},
journal = {Russian Journal of Physical Chemistry A},
year = {2019},
volume = {93},
number = {12},
month = {December},
issn = {0036-0244},
pages = {2472--2476},
numpages = {4},
keywords = {competitive transport; N;N\';N\"-tris(4-methylphenyl)phosphoric triamide carrier; Cu2+ ion; bulk liquid membrane},
}
%0 Journal Article
%T Separation/Competitive Transport of Heavy Metal Ions across the Bulk Liquid Membranes with N,N',N''-Tris(4-methylphenyl)phosphoric Triamide As Carrier
%A ستاره اکبری
%A راضیه ثانوی خشنود
%A Pourayoubi, Mehrdad
%J Russian Journal of Physical Chemistry A
%@ 0036-0244
%D 2019
