Title : ( Influence of hydrogen bond network on supra molecular assembly and gas storage of 2D coordination polymers containing amide/ester ligands )
Authors: Ali Nakhaei Pour ,
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Abstract
In this study, the effects of amide and ester backbones of ligands on the crystal structures and gas storage capability of mercury halide coordination polymers were investigated. Two classes of organic compoundsare Lamide=phenyleneisonicotinamide and Lester=phenyleneisonicotinate ligands. Identical 2D coordination polymers [Hg(Lamide)Cl2]n (1) and [Hg(Lester)Cl2]n (2) were synthesized and characterized by X-ray crystallography. Thermal stability and nitrogen gas sorption capacity of the polymers were investigated and the results showed that these compounds have different properties. In title compounds, 3D hydrogen bonded network formed by C-H…O interactions. These networks have the potential for gas adsorption
Keywords
, Coordination polymer, hydrogen bond, gas adsorption
@inproceedings{paperid:1081196,
author = {Nakhaei Pour, Ali},
title = {Influence of hydrogen bond network on supra molecular assembly and gas storage of 2D coordination polymers containing amide/ester ligands},
booktitle = {7th International Conference on Chemistry and Chemical Engineering,},
year = {2020},
location = {تهران, IRAN},
keywords = {Coordination polymer; hydrogen bond; gas adsorption},
}
%0 Conference Proceedings
%T Influence of hydrogen bond network on supra molecular assembly and gas storage of 2D coordination polymers containing amide/ester ligands
%A Nakhaei Pour, Ali
%J 7th International Conference on Chemistry and Chemical Engineering,
%D 2020
