Title : ( Fischer–Tropsch synthesis over a novel cobalt catalyst supported on UiO-66 )
Authors: NEGIN DAVOODIAN , Ali Nakhaei Pour , Mohammad Izadyar , Ali Mohammadi , Mehdi Vahidi ,
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Abstract
The Fischer–Tropsch synthesis by cobalt catalyst supported on UiO-66 has been evaluated. The prepared UiO-66 support and cobalt-containing catalyst were characterized by XRD, FT-IR, TGA, TPR, oxygen titration, nitrogen adsorption-desorption, and TEM. The catalytic performance was evaluated in Fischer-Tropsch synthesis and compared with conventional porous zirconium promoted Co/SBA-15 catalyst. The Co@UiO-66 catalyst shows higher reducibility of the cobalt due to higher interaction between cobalt and zirconium atoms and lower interaction between cobalt and support in UiO-66 MOF. The Fischer–Tropsch activity of the prepared Co@UiO-66 catalyst is higher than Co/Zr/SBA-15 and the selectivity to methane and long-chain hydrocarbons are lower than the reference catalyst.
Keywords
, Cobalt catalyst; Fischer, Tropsch synthesis; Heterogeneous catalyst; MOFs; UiO, 66.
@article{paperid:1081688,
author = {DAVOODIAN, NEGIN and Nakhaei Pour, Ali and Izadyar, Mohammad and Ali Mohammadi and Mehdi Vahidi},
title = {Fischer–Tropsch synthesis over a novel cobalt catalyst supported on UiO-66},
journal = {Journal of the Iranian Chemical Society},
year = {2020},
volume = {18},
number = {5},
month = {October},
issn = {1735-207X},
pages = {1043--1050},
numpages = {7},
keywords = {Cobalt catalyst; Fischer-Tropsch synthesis; Heterogeneous catalyst; MOFs; UiO-66.},
}
%0 Journal Article
%T Fischer–Tropsch synthesis over a novel cobalt catalyst supported on UiO-66
%A DAVOODIAN, NEGIN
%A Nakhaei Pour, Ali
%A Izadyar, Mohammad
%A Ali Mohammadi
%A Mehdi Vahidi
%J Journal of the Iranian Chemical Society
%@ 1735-207X
%D 2020
