Title : ( Influence of hydrogen bond network onsupramolecular assembly and gas storage of2D coordination polymers containing amide/ester ligands )
Authors: seiede Arghavan Abolghasempour , Alireza Salimi , Ali Nakhaei Pour ,
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Abstract
In this study, the effects of amide and ester backbones of ligands on the crystal structures and gas storage capability of mercury halide coordination polymers were investigated. Two classes of organic compounds are Lamide=phenyleneisonicotinamide and Lester=phenyleneisonicotinate ligands. Identical 2D coordination polymers [Hg(Lamide)Cl2]n (1) and [Hg(Lester)Cl2]n (2) were synthesized and characterized by X-ray crystallography. Thermal stability and nitrogen gas sorption capacity of the polymers were investigated and the results showed that these compounds have different properties. In title compounds, 3D hydrogen bonded network formed by C-H...O interactions. These networks have the potential for gas adsorption.
Keywords
, Coordination polymer, hydrogen bond, gas adsorption
@inproceedings{paperid:1083393,
author = {Abolghasempour, Seiede Arghavan and Salimi, Alireza and Nakhaei Pour, Ali},
title = {Influence of hydrogen bond network onsupramolecular assembly and gas storage of2D coordination polymers containing amide/ester ligands},
booktitle = {هفتمین کنفرانس بین المللی شیمی و مهندسی شیمی},
year = {2020},
location = {تهران, IRAN},
keywords = {Coordination polymer; hydrogen bond; gas adsorption},
}
%0 Conference Proceedings
%T Influence of hydrogen bond network onsupramolecular assembly and gas storage of2D coordination polymers containing amide/ester ligands
%A Abolghasempour, Seiede Arghavan
%A Salimi, Alireza
%A Nakhaei Pour, Ali
%J هفتمین کنفرانس بین المللی شیمی و مهندسی شیمی
%D 2020
