This research focused on developing an eco-friendly packaging for food products through blending polycaprolactone (PCL) and polylactic acid (PLA) as two biodegradable polymers, and green tea extract (GTE) as a natural antioxidant pushing the films toward active packaging; thereby, the morphological, mechanical, thermal, barrier, antioxidant, and biodegradation features of the composite films were analyzed. The films containing 30% PLA exhibited a reduction of 14.96%, 38.89%, 8.75%, and 35.55% in the hydrophilicity, water-solubility, water vapor permeability (WVP), and oxygen transition rate (OTR), respectively. Furthermore, GTE incorporation led to antioxidant behavior as well as better barrier properties (up to 6.25% decrease in WVP and 55.78% in OTR), mechanical properties (an increase of 14.96%, 38.89%, and 8.75% in elastic modulus, tensile strength, and elongation at break, respectively) and biodegradable rate (124.13%). Indeed, the presence of polyphenol compounds in green tea improved molecular interaction between the polymers and launched a co-continuous structure and an unparalleled level of compatibility, which was also approved by the changes in FTIR spectra of the PCL/PLA films. These results demonstrate the benefits of blending PLA with PCL and GTE integration in terms of operational enhancement and film activating, respectively, to provide reliable food packaging.

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