Three coordination complexes {[Cu(pydco)(pz)0.5(H2O)]·H2O}n (1), [Cu(pydco)(phen)(H2O)]·2H2O (2), and [Zn2(pydco)(phen)2Cl2]∙2H2O (3) have been synthesized at room temperature using a mixed-ligand system including pyridine-2,6-dicarboxylic acid N-oxide (H2pydco) as O-donor as well as pyrazine (pz) and 1,10-phenanthroline (phen) as N,N\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\'-bidentate donors. Single-crystal X-ray diffraction (XRD) revealed that 1 forms a 1D-coordination polymer through bridging pz units while 2 and 3 form discrete complexes in which endo-bidentate phen can only connect with one metal centre via a five-membered chelate ring. Also, pydco2– can form a six-membered chelate ring around the metal ion via the N-oxide oxygen and one carboxylate oxygen. However, another carboxylate group of this ligand can also participate in the coordination and create unique structures in 1 and 3. Subsequently, 1-3 can expand their structures into 2D-supramolecular networks through π⋯π stacking or H-bonding interactions. Recurrent π⋯π stacking motifs in all compounds have been further analyzed energetically using DFT calculations and characterized using the quantum theory of “atoms-in-molecules” (QTAIM) and noncovalent interaction plot (NCIPlot) index computational tools. In compound 3, cooperativity effects in π···π/π···π/π···π assemblies have been also analyzed

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