Title : ( Monosubstituted Keggin as heterogeneous catalysts for solvent-free cyanosilylation of aldehydes and ketones )
Authors: Zahra Yekke-Ghasemi , Majid M. Heravi , Masoume Malmir , Masoud Mirzaei Shahrabi ,
Full TextAbstract
Any successful catalyst should have a dedicated synthesizing route considering their high yields, time-efficient, and do not require any highly toxic chemicals. In this regard, two nano-sized monosubstituted polyoxometalates (POMs) with the well-known Keggin structure were synthesized and characterized: (TBA)4[Zr(OH)PW11O39]·22H2O (TBA-ZrPW11) and (TBA)5[Zr(OH)SiW11O39]·17H2O (TBA-ZrSiW11) (TBA+: tetrabutylammonium). Thus, the catalytic activities of both catalysts were tested in the cyanosilylation reaction without any solvents of various aldehydes and ketones with trimethylsilyl cyanide (TMSCN) over two heterogeneous catalysts. Finally, the recyclability and heterogeneity of these POM-based catalysts were also checked, showing that they remain active at least after three recycling procedures.
Keywords
, Zirconium substituted Keggin Heterogeneous catalyst Solvent, free Cyanosilylation TMSCN
@article{paperid:1091216,
author = {Zahra Yekke-Ghasemi and Majid M. Heravi and Masoume Malmir and Mirzaei Shahrabi, Masoud},
title = {Monosubstituted Keggin as heterogeneous catalysts for solvent-free cyanosilylation of aldehydes and ketones},
journal = {Catalysis Communications},
year = {2022},
volume = {171},
number = {171},
month = {November},
issn = {1566-7367},
pages = {106499--106499},
numpages = {0},
keywords = {Zirconium substituted Keggin
Heterogeneous catalyst
Solvent-free
Cyanosilylation
TMSCN},
}
%0 Journal Article
%T Monosubstituted Keggin as heterogeneous catalysts for solvent-free cyanosilylation of aldehydes and ketones
%A Zahra Yekke-Ghasemi
%A Majid M. Heravi
%A Masoume Malmir
%A Mirzaei Shahrabi, Masoud
%J Catalysis Communications
%@ 1566-7367
%D 2022
