Title : ( Boosting the electrocatalytic activity of NiSe by introducing MnCo as an efficient heterostructured electrocatalyst for large-current-density alkaline seawater splitting )
Authors: Reza Andaveh , Alireza Sabour Rouhaghdam , Jianping Ai , Meysam Maleki , Kun Wang , Abdolvahab Seif , Ghasem Barati Darband , Jinyang Li ,Access to full-text not allowed by authors
Abstract
Hydrogen production employing seawater electrolysis is a sustainable strategy for future energy prospects. This study reports high-performance bifunctional water (seawater) electrocatalyst by designing 3-D heterostructured MnCo/NiSe/NF. MnCo/NiSe is concurrently highly energetic toward HER (22.1, 182.8, and 211.6 mV in alkaline water and 31.4, 216.3, and 270.1 mV in alkaline seawater to touch current densities of -10, -500, and -1000 mA cm-2, respectively) and OER (225.8, 340.4, and 370.7 in alkaline water and 261.3, 419.4, and 460.2 mV in alkaline seawater to attain 10, 500, and 1000 mA cm-2, respectively). Interestingly, with cell voltages of 1.41, 1.67, 1.88, and 1.92 V in 1.0 M KOH and 1.44. 1.82, 1.99, and 2.11 V in 1.0 M KOH + seawater to run 10, 100, 500, and 1000 mA cm-2, respectively. DFT based modeling rationalizes our experiments and indicates the synergistic effects between MnCo and NiSe in their complex.
Keywords
Hydrogen evolution reactionElectrocatalystOxygen evolution reactionSeawater splittingDensity functional theory@article{paperid:1092809,
author = {Reza Andaveh and Alireza Sabour Rouhaghdam and Jianping Ai and Meysam Maleki and Kun Wang and Abdolvahab Seif and Barati Darband, Ghasem and Jinyang Li},
title = {Boosting the electrocatalytic activity of NiSe by introducing MnCo as an efficient heterostructured electrocatalyst for large-current-density alkaline seawater splitting},
journal = {Applied Catalysis B: Environmental},
year = {2023},
volume = {325},
month = {May},
issn = {0926-3373},
keywords = {Hydrogen evolution reactionElectrocatalystOxygen evolution reactionSeawater splittingDensity functional theory},
}
%0 Journal Article
%T Boosting the electrocatalytic activity of NiSe by introducing MnCo as an efficient heterostructured electrocatalyst for large-current-density alkaline seawater splitting
%A Reza Andaveh
%A Alireza Sabour Rouhaghdam
%A Jianping Ai
%A Meysam Maleki
%A Kun Wang
%A Abdolvahab Seif
%A Barati Darband, Ghasem
%A Jinyang Li
%J Applied Catalysis B: Environmental
%@ 0926-3373
%D 2023