Rhizosphere, Volume (25), Year (2023-3) , Pages (100664-100674)

Title : ( Synthesis and characterization of the Schiff base Fe(II) complex as a new iron source in nutrient solution )

Authors: Atena mirblok , Mina Alikhani , jalal sadeghi , Amir Lakzian ,

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Abstract

Supplying available iron (Fe) for plant growth in hydroponic nutrient solutions is a great challenge. The chelators commonly used to supply Fe in nutrient solutions have several disadvantages such as the production of photo- degradable compounds and may negatively affect plant growth by toxic side effects on plants and impaired micronutrient balance. Purpose: In this study, a new complex of Fe(II)-triethylenetetramine di salicylaldehyde (Fe-TETDSA) was syn-thesized and applied to a nutrient solution. Methods: Fe-TETDSA was synthesized by the traditional Schiff base prepration method and characterized by FT- IR, Raman, UV–Vis, photoluminescence, molar conductivity and elemental analysis. Fe-TETDSA (with single and double dose) was evaluated as a new Fe source for corns grown in nutrient solution compared to the Fe-EDTA and Fe-EDDHA, as well as FeSO4. Results: The Fe-TETDSA was stable in alkaline pH. Application of Fe-TETDSA chelate significantly increased root and shoot dry weight corns compared to Fe-EDTA and Fe-EDDHA. The total Fe concentration of plants supplied with Fe-TETDSA was more than those supplied with Fe-TETDSA2 and Fe-EDDHA. . Corn plants treated with Fe- TETDSA chelates also accumulated significantly higher levels of Zn (zinc) and N (nitrogen) in their shoots compared with those treated with Fe-EDTA and Fe-EDDHA. But the application of Fe-TETDSA (single and double dose) decreased Cu and Mn concentration in corns shoot. Application of Fe-TETDSA, Fe-TETDSA2 and Fe-EDDHA showed the highest SPAD index in corns leaves. Conclusions: The results showed that Fe-TETDSA may be a sustainable alternative to traditional synthetic chelating agents such as EDTA or EDDHA in nutrient solution

Keywords

, Fe chelate, Corn plant, Fe (II) availability, Hydroponic
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@article{paperid:1094756,
author = {Atena Mirblok and Mina Alikhani and Sadeghi, Jalal and Lakzian, Amir},
title = {Synthesis and characterization of the Schiff base Fe(II) complex as a new iron source in nutrient solution},
journal = {Rhizosphere},
year = {2023},
volume = {25},
month = {March},
issn = {2452-2198},
pages = {100664--100674},
numpages = {10},
keywords = {Fe chelate; Corn plant; Fe (II) availability; Hydroponic},
}

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%0 Journal Article
%T Synthesis and characterization of the Schiff base Fe(II) complex as a new iron source in nutrient solution
%A Atena Mirblok
%A Mina Alikhani
%A Sadeghi, Jalal
%A Lakzian, Amir
%J Rhizosphere
%@ 2452-2198
%D 2023

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