Title : ( Synthesis and structural characterization of nickel(II) coordination complexes with mixed-ligand systems: exploring π−π stacking and hydrogen bonding in supramolecular assemblies )
Authors: Abdulsamad Hamid , Masoud Mirzaei Shahrabi , Maryam Bazargan , Joel T. Mague , Diego M. Gil , Antonio Frontera ,
Full TextAbstract
Two coordination complexes [Ni(Hpydco)2(bpy)] (1) and [Ni(pydco)(phen)(H2O)2]·4.5H2O 0.5CH3OH (2) have been synthesized using a mixed-ligand system including pyridine-2,5-dicarboxylic acid N-oxide (H2pydco) as an O-donor ligand and 2,2\\\\\\\'-bipyridine (bpy) or 1,10-phenanthroline (phen) as a chelating N-donor ligand and NiCl2.6H2O as a source for Ni ions. The crystal structures of 1 and 2 form discrete complexes in which extensive π−π stacking interactions between aromatic rings of the N-donor ligands resulted in the formation of one dimensional (1D) chain-like structures. The chains are connected by hydrogen bonds to expand the structures into 2D-supramolecular networks. Hirshfeld surface analysis and Density Functional Theory (DFT) calculations were included to rationalize the relative strength of the π-stacking assemblies observed in both complexes.
Keywords
, DOI: 10.1007/s13738, 024, 03034, 6 Communication Papers Synthesis and structural characterization of nickel(II) coordination complexes with mixed, ligand systems: exploring π−π stacking and hydrogen bonding in supramolecular assemblies AbdulSamadHamid MasoudMirzaei mirzaeesh@um.ac.ir MaryamBa
@article{paperid:1098810,
author = {Hamid, Abdulsamad and Mirzaei Shahrabi, Masoud and Bazargan, Maryam and جوئل ت. میگ and دیهگو م. گیل and آنتونیو فرانترا},
title = {Synthesis and structural characterization of nickel(II) coordination complexes with mixed-ligand systems: exploring π−π stacking and hydrogen bonding in supramolecular assemblies},
journal = {Journal of the Iranian Chemical Society},
year = {2024},
volume = {21},
number = {8},
month = {September},
issn = {1735-207X},
pages = {1--11},
numpages = {10},
keywords = {DOI: 10.1007/s13738-024-03034-6
Communication Papers
Synthesis and structural characterization of nickel(II) coordination complexes with mixed-ligand systems: exploring π−π stacking and hydrogen bonding in supramolecular assemblies
AbdulSamadHamid
MasoudMirzaei
mirzaeesh@um.ac.ir
MaryamBazargan
JoelT.Mague
DiegoM.Gil
AntonioFrontera
Department of Chemistry; Faculty of ScienceFerdowsi University of MashhadMashhad9177948974Iran
Department of ChemistryTulane UniversityNew OrleansLA70118USA
INBIOFAL (CONICET – UNT); Instituto de Química Orgánica; Facultad de Bioquímica; Química y; FarmaciaUniversidad Nacional de Tucumán471 T4000INIAyacucho San Miguel de TucumánArgentina
Department of ChemistryUniversitat de Les Illes BalearsCrta. de Valldemossa Km 7.507122Palma deMallorca (Baleares)Spain
Received: 1 October 2023 / Accepted: 28 April 2024
Abstract
Two coordination complexes [Ni(Hpydco)2(bpy)] (1) and [Ni(pydco)(phen)(H2O)2]·4.5H2O 0.5CH3OH (2) have been synthesized using a mixed-ligand system including pyridine-2;5-dicarboxylic acid N-oxide (H2pydco) as an O-donor ligand and 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(bpy) or 1;10-phenanthroline (phen) as a chelating N-donor ligand and NiCl2.6H2O as a source for Ni ions. The crystal structures of 1 and 2 form discrete complexes in which extensive π−π stacking interactions between aromatic rings of the N-donor ligands resulted in the formation of one dimensional (1D) chain-like structures. The chains are connected by hydrogen bonds to expand the structures into 2D-supramolecular networks. Hirshfeld surface analysis and Density Functional Theory (DFT)
Pyridine-2;5-dicarboxylic acid N-oxide
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1;10-Phenanthroline
Nickel
Hirshfeld surface analysis
DFT calculations},
}
%0 Journal Article
%T Synthesis and structural characterization of nickel(II) coordination complexes with mixed-ligand systems: exploring π−π stacking and hydrogen bonding in supramolecular assemblies
%A Hamid, Abdulsamad
%A Mirzaei Shahrabi, Masoud
%A Bazargan, Maryam
%A جوئل ت. میگ
%A دیهگو م. گیل
%A آنتونیو فرانترا
%J Journal of the Iranian Chemical Society
%@ 1735-207X
%D 2024
