Applied Catalysis A: General, ( ISI ), Volume (689), Year (2025-1) , Pages (120007-120017)

Title : ( The influence of the catalyst preparation methods on performance of Mn/Na2WO4/SiO2 in oxidative coupling of methane )

Authors: AZAM SOLTANI , Alireza Salimi , Ali Nakhaei Pour , Zahra Nezhadali baghan ,

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Abstract

This study presents various preparation methods for synthesizing a 2 %Mn-4 %Na2WO4/SiO2 catalyst for the oxidative coupling of methane (OCM) using an incipient-wetness impregnation procedure in one/two steps. The catalyst preparation involved modifying various additions and investigating the combination of 4 %, 5 %, and 6 % Na2WO4. Specifically, the effects of operating temperature and the methane-to-oxygen ratio on the catalyst’s performance were investigated. The results suggest that the 2 %Mn-4 %Na2WO4/SiO2 catalyst can operate efficiently under a low methane-to-oxygen feed ratio, making it suitable for OCM reactors. In our packed-bed quartz glass reactor, the dry-impregnated catalyst exhibited excellent performance, with a C2 selectivity of 37.20 %, ethylene selectivity of 13.94 %, ethane subselectivity of 23.26 %, and C2 yield of 28.22 %.

Keywords

Preparation method Heterogeneous catalyst Oxidative coupling Methane C2 selectivity
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@article{paperid:1100852,
author = {SOLTANI, AZAM and Salimi, Alireza and Nakhaei Pour, Ali and زهرا نژاد علی باغان},
title = {The influence of the catalyst preparation methods on performance of Mn/Na2WO4/SiO2 in oxidative coupling of methane},
journal = {Applied Catalysis A: General},
year = {2025},
volume = {689},
month = {January},
issn = {0926-860X},
pages = {120007--120017},
numpages = {10},
keywords = {Preparation method Heterogeneous catalyst Oxidative coupling Methane C2 selectivity},
}

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%0 Journal Article
%T The influence of the catalyst preparation methods on performance of Mn/Na2WO4/SiO2 in oxidative coupling of methane
%A SOLTANI, AZAM
%A Salimi, Alireza
%A Nakhaei Pour, Ali
%A زهرا نژاد علی باغان
%J Applied Catalysis A: General
%@ 0926-860X
%D 2025

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