Title : ( Synthesis of novel fluorescent family of unsymmetric bis(BF2) chromophore: BOPTHY )
Authors: mousa Dehestani , Abbas Ali Esmaeili , Mohammad Reza Housaindokht , Joel T. Mague ,
Full TextAbstract
This paper reported synthesizing a new family of BF2 complexes denoted as BOPTHY via a simple method using commercially available substances. The obtained BOPTHY compounds were well characterized by using FT-IR, 1HNMR, 13CNMR, 19FNMR, and X-ray analysis. These resultant unsymmetrical BODIPY-like compounds (BOPTHY) exhibit high fluorescent properties in solution, and they benefit from their unique structures. Using hydrazine as a connector between thiazole and pyrrole leads to getting bis boron difluoride complexes with a supreme molar absorption coefficient (38,900–47,000 M-1 cm-1), large Stokes shifts, brilliant pH-stability, environmentally sensitive to pH and polarity, and high fluorescence quantum yields. Notably, the photo properties of the synthesized compounds were further confirmed through the DFT calculation
Keywords
, BF2 complexes, BOPTHY, Solution phase, Stokes shifts, BODIPY, DFT calculation
@article{paperid:1101215,
author = {Dehestani, Mousa and Esmaeili, Abbas Ali and Housaindokht, Mohammad Reza and ژول ت. مگ},
title = {Synthesis of novel fluorescent family of unsymmetric bis(BF2) chromophore: BOPTHY},
journal = {Journal of Molecular Structure},
year = {2025},
volume = {1327},
month = {April},
issn = {0022-2860},
pages = {141137--141146},
numpages = {9},
keywords = {BF2 complexes; BOPTHY; Solution phase; Stokes shifts; BODIPY; DFT calculation},
}
%0 Journal Article
%T Synthesis of novel fluorescent family of unsymmetric bis(BF2) chromophore: BOPTHY
%A Dehestani, Mousa
%A Esmaeili, Abbas Ali
%A Housaindokht, Mohammad Reza
%A ژول ت. مگ
%J Journal of Molecular Structure
%@ 0022-2860
%D 2025
