Title : ( Investigating the Effect of Current Density on Electrodeposited Ni-TiC-WC Composite Coating and Evaluating the Corrosion Resistance of the Coating and Substrate in NaCl Solution )
Authors: Ali Keramatian , Mohammad Hossein Enayati , Fatemehsadat Sayyedan , Sima Torkian ,
Abstract
This study aimed to investigate the effect of current density on the microstructure of electrodeposited Ni–WC–TiC composite coatings on 304 stainless steel and compare the corrosion resistance of the coating and substrate in a 3.5 wt.% sodium chloride solution. A Watts nickel bath was employed under direct current (DC) conditions. Microstructure, elemental composition, and phase composition analyses were conducted using scanning electron microscopy (SEM) equipped with energy-dispersive X-ray spectroscopy (EDS) and X-ray diffraction (XRD), respectively. The results revealed that the coating formed at a current density of 40 mA/cm² exhibited a denser microstructure with higher cohesion and uniformity than coatings produced at other current densities. The corrosion resistance of the coating and substrate was evaluated using Tafel and electrochemical impedance spectroscopy (EIS) analyses. The corrosion test results indicated that the substrate exhibited superior corrosion resistance compared to the coating. Based on the dynamic polarization test plots, the corrosion mechanism of the substrate is activequasi passive, with a pseudo-passive layer forming on the sample, which remains stable within the potential range of -0.17 to 0.17 V. Beyond this likely range, the sample becomes susceptible to pitting. In the coated sample, the corrosion behavior is similar to that of the substrate, except that the pseudo-passive layer remains stable within a narrower potential range of -0.19 to 0.08 V.
Keywords
, Electrodeposition, Ni–WC–TiC, Composite coating, Corrosion resistance.@article{paperid:1103301,
author = {علی کرامتیان and محمد حسین عنایتی and Fatemehsadat Sayyedan, and سیما ترکیان},
title = {Investigating the Effect of Current Density on Electrodeposited Ni-TiC-WC Composite Coating and Evaluating the Corrosion Resistance of the Coating and Substrate in NaCl Solution},
journal = {Iranian Journal of Materials Science and Engineering},
year = {2025},
volume = {22},
number = {2},
month = {June},
issn = {1735-0808},
pages = {49--57},
numpages = {8},
keywords = {Electrodeposition; Ni–WC–TiC; Composite coating; Corrosion resistance.},
}
%0 Journal Article
%T Investigating the Effect of Current Density on Electrodeposited Ni-TiC-WC Composite Coating and Evaluating the Corrosion Resistance of the Coating and Substrate in NaCl Solution
%A علی کرامتیان
%A محمد حسین عنایتی
%A Fatemehsadat Sayyedan,
%A سیما ترکیان
%J Iranian Journal of Materials Science and Engineering
%@ 1735-0808
%D 2025