Journal of the Australian Ceramic Society, Year (2025-12)

Title : ( An investigation on the hot corrosion behavior of mullite-12wt.%Yb2SiO5 as a novel EBC composite under CMAS melt attack )

Authors: Alireza Hasani Arefi , Majid Mohammadi , Mostafa Hajian , Mahla Seif Zadeh , Seyed Abdolkarim Sajjadi ,

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Abstract

Environmental barrier coatings (EBCs) are used to protect silicon carbide (SiC) components in gas turbine engines by inhibiting their surface reactions with water vapor and molten calcium-magnesium-alumino-silicates (CMAS). In this study, ytterbium monosilicate (Yb2SiO5) and mullite (3Al2O3.2SiO2) powders were synthesized and mixed with a specific content (mullite-12wt.%Yb2SiO5) as an EBC. The hot corrosion performance of the composite samples was investigated at 1300 °C for various durations in contact with molten CMAS powder. Phase analysis of the synthesized powders and hot-corroded specimens was characterized using the X-ray diffraction (XRD) technique. A scanning electron microscope (SEM) equipped with an energy-dispersive spectrometer (EDS) was used to study the morphology and chemical composi-tion of phases formed in the hot-corroded samples. The results showed that as the exposure time increased up to 48 h, the rate of reaction-layer growth significantly decreased, indicating enhanced substrate protection at high temperatures. Additionally, the formation of resistant phases, such as Yb₃Al₅O₁₂ and anorthite, during the reaction leads to an improvement in coating performance. These findings highlight the potential of Yb₂SiO₅-based EBCs for advanced gas turbine applications.

Keywords

, Environmental barrier coatings · Hot corrosion · Mullite, Yb2SiO5 · CMAS melt
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@article{paperid:1106047,
author = {Hasani Arefi, Alireza and مجید محمدی and مصطفی حاجیان and Seif Zadeh , Mahla and Sajjadi, Seyed Abdolkarim},
title = {An investigation on the hot corrosion behavior of mullite-12wt.%Yb2SiO5 as a novel EBC composite under CMAS melt attack},
journal = {Journal of the Australian Ceramic Society},
year = {2025},
month = {December},
issn = {2510-1560},
keywords = {Environmental barrier coatings · Hot corrosion · Mullite-Yb2SiO5 · CMAS melt},
}

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%0 Journal Article
%T An investigation on the hot corrosion behavior of mullite-12wt.%Yb2SiO5 as a novel EBC composite under CMAS melt attack
%A Hasani Arefi, Alireza
%A مجید محمدی
%A مصطفی حاجیان
%A Seif Zadeh , Mahla
%A Sajjadi, Seyed Abdolkarim
%J Journal of the Australian Ceramic Society
%@ 2510-1560
%D 2025

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