Thermochimica Acta, ( ISI ), Year (2006-3)

Title : Application of a new equation of state to liquid refrigerant mixtures ( Application of a new equation of state to liquid refrigerant mixtures )

Authors: Elaheh Kafshdare Goharshadi , majid mossavi ,

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A new general equation of state recently reported for pure liquids has been developed to predict the volumetric and thermodynamic properties of six binary and two ternary liquid refrigerant mixtures (including HCs and HFCs mixtures) at different temperatures, pressures, and compositions. The results show this equation of state can be used to reproduce and predict different thermodynamic properties of liquid refrigerant mixtures within experimental errors. The composition dependence of the parameters of this equation of state has been assumed as quadratic functions of mole fraction. Using these mixing rules, the agreement between calculated and experimental densities is better than 0.6% for binary mixtures and 2.3% for ternary mixtures. To compare the performance of this new equation of state against other well-known methods such as the COSTALD method, the density of some refrigerant mixtures, for which the parameters of COSTALD were available, has been computed and compared with those of this new equation of state.

Keywords

GMA EoS; Liquids; Internal pressure; Refrigerant mixtures; Statistical thermodynamics; Volumetric
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@article{paperid:202518,
author = {Kafshdare Goharshadi, Elaheh and Mossavi, Majid},
title = {Application of a new equation of state to liquid refrigerant mixtures},
journal = {Thermochimica Acta},
year = {2006},
month = {March},
issn = {0040-6031},
keywords = {GMA EoS; Liquids; Internal pressure; Refrigerant mixtures; Statistical thermodynamics; Volumetric properties},
}

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%0 Journal Article
%T Application of a new equation of state to liquid refrigerant mixtures
%A Kafshdare Goharshadi, Elaheh
%A Mossavi, Majid
%J Thermochimica Acta
%@ 0040-6031
%D 2006

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