Title : ( A Novel and Highly Selective Conversion of Alcohols, Thiols, and Silyl Ethers to Azides usingthe 2,4,6-Trichloro[1,3,5]triazine/n-Bu4NN3 System )
Authors: سیما سمیعی * , Batool Akhlaghinia ,
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Abstract
Alkyl azides are prepared in good to excellent yields by treatment of alcohols, thiols and trimethylsilyl ethers with 2,4,6-trichloro[1,3,5]triazine/n-Bu4NN 3 in acetonitrile. This method is highly selective for conversion of primary alcohols to alkyl azides in the presence of secondary and tertiary alcohols, thiols and trimethysilyl ethers.
Keywords
, 2, 4, 6-trichloro[1, 3, 5] triazine (TT), alcohol, thiol, trimethylsilyl ether, alkyl azide
@article{paperid:1008590,
author = {سیما سمیعی * and Akhlaghinia, Batool},
title = {A Novel and Highly Selective Conversion of Alcohols, Thiols, and Silyl Ethers to Azides usingthe 2,4,6-Trichloro[1,3,5]triazine/n-Bu4NN3 System},
journal = {Journal of the Brazilian Chemical Society},
year = {2007},
month = {July},
issn = {0103-5053},
keywords = {2;4;6-trichloro[1;3;5] triazine (TT); alcohol; thiol; trimethylsilyl ether; alkyl
azide},
}
%0 Journal Article
%T A Novel and Highly Selective Conversion of Alcohols, Thiols, and Silyl Ethers to Azides usingthe 2,4,6-Trichloro[1,3,5]triazine/n-Bu4NN3 System
%A سیما سمیعی *
%A Akhlaghinia, Batool
%J Journal of the Brazilian Chemical Society
%@ 0103-5053
%D 2007
