Structural Chemistry, ( ISI ), Volume (19), Year (2008-10) , Pages (895-903)

Title : ( Synthesis, crystal structure of new linear trinuclear isovalence Co(II)([Co3(H-L)2(L)2]), and visualizing intermolecular interactions with Hirshfeld surface method )

Authors: Mohammad Yazdanbakhsh , Reza Takjoo ,

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S-allyl-b-N-[(2-hydroxyphenyl)methylene]hyrazinecarbodithioate) (1, H2L), the Schiff base of dithiocarbazate with unsatd. allyl substitution, can act as a new tridentate SNO ligand H2-L and react with cobalt(II) nitrate hexahydrate to form the novel linear trinuclear isovalence Co(II) complex, [Co3(H-L)2(L)2] 2C2H5OH (2). The compds. were characterized by elemental anal., IR, and UV spectroscopy. Compd. 2 was also characterized by single-crystal X-ray anal. and crystallizes in the orthorhombic space group, Pbcn, with a = 30.643(1) .ANG., b = 9.118(4) .ANG., c = 19.017(7) .ANG., a = b = g = 90°, V = 5312.95 .ANG.3, Z = 4, and R 1 = 0.0790, (wR 2) = 0.1223. The six-coordinate central Co(II) atom is bonded to two deprotonated metal-contg. ligands. The terminal Co(II) atoms are in a square planar SNON four-coordinate environment and connected to the central Co(II) by N-atoms from the ligand backbone. For quantifying the intermol. interactions in crystal lattice, the new d norm surface and the breakdown of fingerprint plots have been used for visualizing and exploring the compd. 2.

Keywords

, Trinuclear cobalt complex, S-allyldithiocarbazate, Crystal structure, Schiff base, Hirshfeld
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@article{paperid:1009437,
author = {Yazdanbakhsh, Mohammad and Takjoo, Reza},
title = {Synthesis, crystal structure of new linear trinuclear isovalence Co(II)([Co3(H-L)2(L)2]), and visualizing intermolecular interactions with Hirshfeld surface method},
journal = {Structural Chemistry},
year = {2008},
volume = {19},
month = {October},
issn = {1040-0400},
pages = {895--903},
numpages = {8},
keywords = {Trinuclear cobalt complex; S-allyldithiocarbazate; Crystal structure; Schiff base; Hirshfeld surface},
}

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%0 Journal Article
%T Synthesis, crystal structure of new linear trinuclear isovalence Co(II)([Co3(H-L)2(L)2]), and visualizing intermolecular interactions with Hirshfeld surface method
%A Yazdanbakhsh, Mohammad
%A Takjoo, Reza
%J Structural Chemistry
%@ 1040-0400
%D 2008

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