In this paper, modeling and simulation of combustion process for polybrominated diphenyl ethers in rotary kilns has been investigated. Proper formula is found for the solid wastes which contain polybrominated diphenyl ethers and then combustion process is simulated by considering possible reactions, appropriate dimensions and operating conditions for rotary kiln, and necessary relations for reaction rates. The software of MATLAB is used for the simulation. The mass variations for solid waste, outlet gas and its components are calculated during twenty hours. The results show that the reaction rate is high for the first two hours, so the value of solid waste and oxygen decrease quickly while value of produced gases increases. The mass increase of polychlorinated dibenzo-p-dioxins/furans and polybrominated dibenzo-p-dioxins/furans during the whole time of the process is linear with mild slope but for the other compounds including steam, carbon dioxide, nitrogen, nitrogen oxide, sulphur dioxide, hydrogen chloride and hydrogen bromine, the slope of variations becomes mild after three hours. The process becomes steady state almost after nine hours.

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